Article
  • Bio-based Copolyester Fibers: Polymerization and Melt Spinning of Poly(ethylene 2,5-furandicarboxylate-co-propylene 2,5-furandicarboxylate)
  • Jimin Baek, Seongil Yu, Seungjae Ahn*, and Ki-Young Kim

  • Material & Component Convergence R&D Department, Korea Institute of Industrial Technology (KITECH), 143, Hanggaul-ro, Sangnok-gu, Ansan-si, Gyeonggi-do 15588, Korea
    *ESC Coprosperity Division, Korea High Tech Textile Research Institute, 170, Geomjun-gil, Nam-myeon, Yangju-si, Gyeonggi-do 11410, Korea

  • 바이오 기반 Copolyester 섬유: Poly(ethylene 2,5-furandicarboxylate-co-propylene 2,5-furandicarboxylate)의 중합 및 용융방사
  • 백지민 ·유성일 · 안승재* · 김기영

  • 한국생산기술연구원 소재부품융합연구부문, *한국섬유소재연구원 ESC상생본부

  • Reproduction, stored in a retrieval system, or transmitted in any form of any part of this publication is permitted only by written permission from the Polymer Society of Korea.

References
  • 1. Iwata, T. Biodegradable and Bio-Based Polymers: Future Prospects of Eco-Friendly Plastics. Angew. Chem. Int. Ed. Engl. 2015, 54, 3210-3215.
  •  
  • 2. Vink, E. T.; Rabago, K. R.; Glassner, D. A.; Gruber, P. R. Applications of Life Cycle Assessment to NatureWorksTM Polylactide (PLA) Production. Polym. Degrad. Stab. 2003, 80, 403-419.
  •  
  • 3. Zhu, J.; Cai, J.; Xie, W.; Chen, P. H.; Gazzano, M.; Scandola, M.; Gross, R. A. Poly(butylene 2,5-furan dicarboxylate), a Biobased Alternative to PBT: Synthesis, Physical Properties, and Crystal Structure. Macromolecules 2013, 46, 796-804.
  •  
  • 4. Gandini, A. The Irruption of Polymers from Renewable Resources on the Scene of Macromolecular Science and Technology. Green Chem. 2011, 13, 1061-1083.
  •  
  • 5. Gallezot, P. Conversion of Biomass to Selected Chemical Products. Chem. Soc. Rev. 2012, 41, 1538-1558.
  •  
  • 6. Zhang, Z.; Deng, K. Recent Advances in the Catalytic Synthesis of 2,5-Furandicarboxylic Acid and Its Derivatives. ACS Catal. 2015, 5, 6529-6544.
  •  
  • 7. Davis, S. E.; Zope, B. N.; Davis, R. J. On the Mechanism of Selective Oxidation of 5-Hydroxymethylfurfural to 2,5-Furandi- carboxylic Acid Over Supported Pt and Au Catalysts. Green Chem. 2012, 14, 143-147.
  •  
  • 8. Sousa, A. F.; Vilela, C.; Fonseca, A. C.; Matos, M.; Freire, C. S.; Gruter, G. J. M.; Coelho, J. F.; Silvestre, A. J. Biobased Polyesters and Other Polymers from 2,5-Furandicarboxylic Acid: A Tribute to Furan Excellency. Polym. Chem. 2015, 6, 5961-5983.
  •  
  • 9. Gandini, A.; Silvestre, A. J.; Neto, C. P.; Sousa, A. F.; Gomes, M. The Furan Counterpart of Poly(ethylene terephthalate): An Alternative Material Based on Renewable Resources. J. Polym. Sci. Part A: Polym. Chem. 2009, 47, 295-298.
  •  
  • 10. Guidotti, G.; Soccio, M.; Lotti, N.; Gazzano, M.; Siracusa, V.; Munari, A. Poly(propylene 2,5-thiophenedicarboxylate) vs. Poly- (propylene 2,5-furandicarboxylate): Two Examples of High Gas Barrier Bio-Based Polyesters. Polymers 2018, 10, 785-798.
  •  
  • 11. Soccio, M.; Costa, M.; Lotti, N.; Gazzano, N.; Siracusa, V.; Salatelli, E.; Manaresi, P.; Munari, A. Novel Fully Biobased Poly(butylene 2,5-furanoate/diglycolate) Copolymers Containing Ether Linkages: Structure-Property Relationships. Eur. Polym. J. 2016, 81, 397-412.
  •  
  • 12. Sun, L.; Wang, J.; Mahmud, S.; Jiang, Y.; Zhu, J.; Liu, X. New Insight into the Mechanism for the Excellent Gas Properties of Poly(ethylene 2,5-furandicarboxylate) (PEF): Role of Furan Ring’s Polarity. Eur. Polym. J. 2019, 118, 642-650.
  •  
  • 13. Burgess, S. K.; Leisen, J. E.; Kraftschik, B. E.; Mubarak, C. R.; Kriegel, R. M.; Koros, W. J. Chain Mobility, Thermal, and Mechanical Properties of Poly(ethylene furanoate) Compared to Poly(ethylene terephthalate). Macromolecules 2014, 47, 1383-1391.
  •  
  • 14. Vannini, M.; Marchese, P.; Celli, A.; Lorenzetti, C. Fully Biobased Poly(propylene 2,5-furandicarboxylate) for Packaging Applications: Excellent Barrier Properties as A Function of Crystallinity. Green Chem. 2015, 17, 4162-4166.
  •  
  • 15. Ward, I. M.; Wilding, M. A.; Brody, H. The Mechanical Properties and Structure of Poly(m-methylene Terephthalate) Fibers. J. Polym. Sci. Part B: Polym. Phys. 1976, 14, 263-274.
  •  
  • 16. Bikiaris, D. N.; Papageorgiou, G. Z.; Achilias, D. S. Synthesis and Comparative Biodegradability Studies of Three Poly(alkylene succinate)s. Polym. Degrad. Stab. 2006, 91, 31-43.
  •  
  • 17. Fineman, M.; Ross, S. D. Linear Method for Determining Monomer Reactivity Ratios in Copolymerization. J. Polym. Sci. 1950, 5, 259-265.
  •  
  • 18. Konstantopoulou, M.; Terzopoulou, Z.; Nerantzaki, M.; Tsagkalias, J.; Achilias, D. S.; Bikiaris, D. N.; Exarhopoulos, S.; Papageorgiou, D. G.; Papageorgiou, G. Z. Poly(ethylene furanoate-co-ethylene terephthalate) Biobased Copolymers: Synthesis, Thermal Properties and Cocrystallization Behavior. Eur. Polym. J. 2017, 89, 349-366.
  •  
  • 19. Tsanaktsis, V.; Vouvoudi, E.; Papageorgiou, G. Z.; Papageorgiou, D. G.; Chrissafis, K.; Bikiaris, D. N. Thermal Degradation Kinetics and Decomposition Mechanism of Polyesters Based on 2,5-Furandicarboxylic Acid and Low Molecular Weight Aliphatic Diols. J. Anal. Appl. Pyrolysis 2015, 112, 369-378.
  •  
  • 20. Papadopoulos, L.; Magaziotis, A.; Nerantzaki, M.; Terzopoulou, Z.; Papageorgiou, G. Z.; Bikiaris, D. N. Synthesis and Characterization of Novel Poly(ethylene furanoate-coadipate) Random Copolyesters with Enhanced Biodegradability. Polym. Degrad. Stab. 2003, 156, 32-42.
  •  
  • 21. Ward, I. M. The Molecular Structure and Mechanical Properties of Polyethylene Terephthalate Fibers. Text. Res. J. 1961, 31, 650-664.
  •  
  • Polymer(Korea) 폴리머
  • Frequency : Bimonthly(odd)
    ISSN 0379-153X(Print)
    ISSN 2234-8077(Online)
    Abbr. Polym. Korea
  • 2021 Impact Factor : 0.473
  • Indexed in SCIE

This Article

  • 2022; 46(3): 382-388

    Published online May 25, 2022

  • 10.7317/pk.2022.46.3.382
  • Received on Feb 4, 2022
  • Revised on Mar 24, 2022
  • Accepted on Mar 31, 2022

Correspondence to

  • Ki-Young Kim
  • Material & Component Convergence R&D Department, Korea Institute of Industrial Technology (KITECH), 143, Hanggaul-ro, Sangnok-gu, Ansan-si, Gyeonggi-do 15588, Korea

  • E-mail: kkim@kitech.re.kr