• Controlling Hydrophobicity and Oleophobicity of Silica Hybrid Particles through UV/ozone Surface Treatment
  • Keumjung Lee# , Seo Yeon Park# , Hye Yun Park, Ju Yeon Myeong, Jin-Wook Lee*, Sung-Hun Lim**, and Jun Hyup Lee

  • Department of Chemical Engineering, Soongsil University, Seoul 06978, Korea
    *School of Mechanical Engineering, Soongsil University, Seoul 06978, Korea
    **School of Electrical Engineering, Soongsil University, Seoul 06978, Korea

  • UV/O3 표면처리를 이용한 실리카 하이브리드 입자의 발수성 및 발유성 제어
  • 이금정# · 박서연# · 박혜윤 · 명주연 · 이진욱* · 임성훈** · 이준협

  • 숭실대학교공과대학화학공학과, *숭실대학교공과대학기계공학부, **숭실대학교공과대학전기공학부

  • Reproduction, stored in a retrieval system, or transmitted in any form of any part of this publication is permitted only by written permission from the Polymer Society of Korea.


References
  • 1. Jeelani, P. G.; Mulay, P.; Venkat, R.; Ramalingam, C. Multifaceted Application of Silica Nanoparticles. A Review. Silicon 2020, 12, 1337-1354.
  •  
  • 2. Radin, S.; El-Bassyouni, G.; Vresilovic, E. J.; Schepers, E.; Ducheyne, P. In Vivo Tissue Response to Resorbable Silica Xerogels as Controlled-release Materials. Biomaterials 2005, 26, 1043-1052.
  •  
  • 3. Lu, J.; Liong, M.; Zink, J. I.; Tamanoi, F. Mesoporous Silica Nanoparticles as a Delivery System for Hydrophobic Anticancer Drugs. Small 2007, 3, 1341-1346.
  •  
  • 4. Niculescu, V. C. Mesoporous Silica Nanoparticles for Bio-Applications. Front. Mater. 2020, 7, 36.
  •  
  • 5. Jeon, M.-O.; Chang, B.-S. Property of Silica and Fine Structure of Cosmetic White Powders. Korean J. Microsc. 2012, 42, 87-93.
  •  
  • 6. Jaroenworaluck, A.; Sunsaneeyametha, W.; Kosachan, N.; Stevens, R. Characteristics of Silica-coated TiO2 and Its UV Absorption for Sunscreen Cosmetic Applications. Surf. Interface Anal. 2006, 38, 1380-1385.
  •  
  • 7. Martin, K. R. The Chemistry of Silica and Its Potential Health Benefits. J. Nutr. Health Aging. 2007, 11, 94-97.
  •  
  • 8. Hu, Y.; Hao, D.; Gong, F.; Gao, Y.; Yan, X.; Ma, G. Facile One-pot Emulsion/sol-gel Method for Preparing Wrinkled Silica Microspheres. Particuology 2021, 56, 33-42.
  •  
  • 9. Kraus, T.; Brodoceanu, D.; Pazos-Perez, N.; Fery, A. Colloidal Surface Assemblies: Nanotechnology Meets Bioinspiration. Adv. Funct. Mater. 2013, 23, 4529-4541.
  •  
  • 10. Lefebvre, G.; Galet, L.; Chamayou, A. Dry Coating of Talc Particles with Fumed Silica: Influence of the Silica Concentration on the Wettability and Dispersibility of the Composite Particles. Powder Technol. 2011, 208, 372-377.
  •  
  • 11. Yang, J.; Sliva, A.; Banerjee, A.; Dave, R. N.; Pfeffer, R. Dry Particle Coating for Improving the Flowability of Cohesive Powders. Powder Technol. 2005, 158, 21-33.
  •  
  • 12. Wang, F.; Wang, X.; Xie, A.; Shen, Y.; Duan, W.; Zhang, Y.; Li, J. A Simple Method for Preparation of Transparent Hydrophobic Silica-based Coatings on Different Substrates. Appl. Phys. A. 2012, 106, 229-235.
  •  
  • 13. Ogihara, H.; Xie, J.; Okagaki, J.; Saji, T. Simple Method for Preparing Superhydrophobic Paper: Spray-deposited Hydrophobic Silica Nanoparticle Coatings Exhibit High Water-repellency and Transparency. Langmuir 2012, 28, 4605-4608.
  •  
  • 14. Santawisuk, W.; Kanchanavasita, W.; Sirisinha, C.; Harnirattisai, C. Dynamic Viscoelastic Properties of Experimental Silicone Soft Lining Materials. Dent. Mater. J. 2010, 29, 454-460.
  •  
  • 15. Ulker, Z.; Erkey, C. An Emerging Platform for Drug Delivery: Aerogel Based Systems. J. Control. Release 2014, 177, 51-63.
  •  
  • 16. Kuwahara, Y.; Maki, K.; Matsumura, Y.; Kamegawa, T.; Mori, K.; Yamashita, H. Hydrophobic Modification of a Mesoporous Silica Surface Using a Fluorine-containing Silylation Agent and Its Application as an Advantageous Host Material for the TiO2 Photocatalyst. J. Phys. Chem. C. 2009, 113, 1552-1559.
  •  
  • 17. Liu, S.; Peng, Y.; Chen, J.; Shi, W.; Yan, T.; Li, B.; Zhang, Y.; Li, J. Engineering Surface Functional Groups on Mesoporous Silica: Towards a Humidity-resistant Hydrophobic Adsorbent. J. Mater. Chem. A 2018, 6, 13769-13777.
  •  
  • 18. Duchet, J.; Gerard, J. F.; Chapel, J. P.; Chabert, B. Grafting of Alkylchlorosilanes onto Silica from Solution for Adhesion Enhancement. J. Adhes. Sci. Technol. 2000, 14, 691-718.
  •  
  • 19. Cui, L.; Zhou, Q. F.; Liao, C. Y.; Fu, J. J.; Jiang, G. Bin. Studies on the Toxicological Effects of PFOA and PFOS on Rats Using Histological Observation and Chemical Analysis. Arch. Environ. Contam. Toxicol. 2009, 56, 338-349.
  •  
  • 20. Yardley-Jones, A.; Anderson, D.; Parke, D. V. The Toxicity of Benzene and Its Metabolism and Molecular Pathology in Human Risk Assessment. Occup. Environ. Med. 1991, 48, 437-444.
  •  
  • 21. Garson, L. R.; Kirchner, L. K. Organosilicon Entities as Prophylactic and Therapeutic Agents. J. Pharm. Sci. 1971, 60, 1113-1127.
  •  
  • 22. Victor, A.; Ribeiro, J.; Araújo, F. Study of PDMS Characterization and Its Applications in Biomedicine: A Review. J. Mech. Eng. Biomech.2019, 4, 1-9.
  •  
  • 23. Smirnova, I.; Suttiruengwong, S.; Arlt, W. Feasibility Study of Hydrophilic and Hydrophobic Silica Aerogels as Drug Delivery Systems. J. Non-Cryst. Solids 2004, 350, 54-60.
  •  
  • 24. Lee, D.; Yang, S. Surface Modification of PDMS by Atmospheric-pressure Plasma-enhanced Chemical Vapor Deposition and Analysis of Long-lasting Surface Hydrophilicity. Sens. Actuators B: Chem. 2012, 162, 425-434.
  •  
  • 25. Maji, D.; Lahiri, S. K.; Das, S. Study of Hydrophilicity and Stability of Chemically Modified PDMS Surface Using Piranha and KOH Solution. Surf. Interface Anal. 2012, 44, 62-69.
  •  
  • 26. Slaughter, G.; Stevens, B. A Cost-effective Two-step Method for Enhancing the Hydrophilicity of PDMS Surfaces. Biochip J. 2014, 8, 28-34.
  •  
  • 27. Niu, Z.; Gao, F.; Jia, X.; Zhang, W.; Chen, W.; Qian, K. Synthesis Studies of Sputtering TiO2 Films on Poly(dimethylsiloxane) for Surface Modification. Colloids Surf. A: Physicochem. Eng. Asp. 2006, 272, 170-175.
  •  
  • 28. Oláh, A.; Hillborg, H.; Vancso, G. J. Hydrophobic Recovery of UV/ozone Treated Poly(dimethylsiloxane): Adhesion Studies by Contact Mechanics and Mechanism of Surface Modification. Appl. Surf. Sci. 2005, 239, 410-423.
  •  
  • 29. Ouyang, M.; Yuan, C.; Muisener, R. J.; Boulares, A.; Koberstein, J. T. Conversion of Some Siloxane Polymers to Silicon Oxide by UV/ozone Photochemical Processes. Chem. Mater. 2000, 12, 1591-1596.
  •  
  • 30. Fu, Y. J.; Qui, H. Z.; Liao, K. S.; Lue, S. J.; Hu, C. C.; Lee, K. R.; Lai, J. Y. Effect of UV-ozone Treatment on Poly(dimethylsiloxane) Membranes: Surface Characterization and Gas Separation Performance. Langmuir 2010, 26, 4392-4399.
  •  
  • 31. Bilgin, S.; Isik, M.; Yilgor, E.; Yilgor, I. Hydrophilization of Silicone-Urea Copolymer Surfaces by UV/ozone: Influence of PDMS Molecular Weight on Surface Oxidation and Hydrophobic Recovery. Polymer 2013, 54, 6665-6675.
  •  
  • 32. Park, C. B.; Kim, S. H.; Lee, K.; Lee, J. H. Controlling Superhydrophobicity and Oleophobicity of Polydimethylsiloxane-coated Silica Hybrid Particles. Langmuir 2023, 39, 4829-4837.
  •  
  • 33. Zhou, Q.; Xiang, H.; Fan, H.; Yang, X.; Zhao, N.; Xu, J. Facile Fabrication of Golf Ball-like Hollow Microspheres of Organic-inorganic Silica. J. Mater. Chem. 2011, 21, 13056-13061.
  •  
  • 34. Compoint, F.; Fall, D.; Piombini, H.; Belleville, P.; Montouillout, Y.; Duquennoy, M.; Ouaftouh, M.; Jenot, F.; Piwakowski, B.; Sanchez, C. Sol–gel-processed Hybrid Silica-PDMS Layers for the Optics of High-power Laser Flux Systems. J. Mater. Sci. 2016, 51, 5031-5045.
  •  
  • 35. Hair M. L. Hydroxyl Groups on Silica Surface. J. Non-Cryst. Solids 1975, 19, 299-309.
  •  
  • 36. Darmawan, A.; Utari, R.; Saputra, R. E.; Suhartana; Astuti, Y. Synthesis and Characterization of Hydrophobic Silica Thin Layer Derived from Methyltrimethoxysilane (MTMS). IOP Conf. Ser.: Mater. Sci. Eng. 2018, 299, 012041.
  •  
  • 37. De Menezes Atayde, C.; Doi, I. Highly Stable Hydrophilic Surfaces of PDMS Thin Layer Obtained by UV Radiation and Oxygen Plasma Treatments. Phys. Status Solidi C 2010, 7, 189-192.
  •  
  • 38. Wilmsmeyer, A. R.; Gordon, W. O.; Davis, E. D.; Troya, D.; Mantooth, B. A.; Lalain, T. A.; Morris, J. R. Infrared Spectra and Binding Energies of Chemical Warfare Nerve Agent Simulants on the Surface of Amorphous Silica. J. Phys. Chem. C. 2013, 117, 15685-15697.
  •  
  • Polymer(Korea) 폴리머
  • Frequency : Bimonthly(odd)
    ISSN 2234-8077(Online)
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This Article

  • 2026; 50(2): 331-339

    Published online Mar 25, 2026

  • 10.7317/pk.2026.50.2.331
  • Received on Nov 17, 2025
  • Revised on Nov 24, 2025
  • Accepted on Nov 25, 2025

Correspondence to

  • Jun Hyup Lee
  • Department of Chemical Engineering, Soongsil University, Seoul 06978, Korea

  • E-mail: junhyuplee@ssu.ac.kr