• A Study on Thermal and Mechanical Properties of Vapor Grown Carbon Nanofibers-Reinforced Epoxy Matrix Composites
  • Park SJ, Lee EJ, Lee JR
  • 기상성장 탄소나노섬유/에폭시 복합재료위 열적 및 기계적 특성에 관한 연구
  • 박수진, 이은정, 이재락
Abstract
In this work, the thermal and mechanical properties of vapor grown carbon nanofibers (VGCNFs)-reinforced difunctional epoxy (EP) composites were investigated in the presence of the 0, 0.1, 0.5, 1.0, and 2.0 wt% VGCNFs. The thermal properties of the VGCNFs/EP composites were studied by thermo-mechanical analysis (TMA) and dynamic mechanical analysis (DMA). The mechanical properties of the VGCNFs/EP composites were also examined by universal testing machine (UTM), falling impact test, and the friction and wear tests. From experimental results, the thermal and mecahnical properties of the VGCNFs/EP composites were improved with increasing the VGCNFs contents. This was due to the increase of crosslinking structure of the composites, resulting in improving the mechanical interlockings between VGCNFs and epoxy resins in the present composite system.

본 연구에서는 2관능성 에폭시 수지에 기상성장 탄소나노섬유(VGCNFs)를 0, 0.1, 0.5, 1.0 그리고 2.0 wt% 함량비로 첨가하여, 제조한 VGCNFs/에폭시 복합재료의 열적 및 기계적 특성을 고찰하고자 하였다. VGCNFs/에폭시 나노 복합재료의 열적 특성은 TMA와 DMA로 알아 보았으며, 기계적 특성은 만능 시험기와 낙하 충격 시험기 및 마찰ㆍ마모 시험기를 통하여 관찰하였다. 실험 결과, VGCNFs 함량이 증가할수록 열적 및 기계적 특성이 향상됨을 확인할 수 있었는데, 이는 현재의 복합재료 시스템에 있어서 VGCNFs와 에폭시 사이의 기계적 얽힘 현상의 향상을 가져오는 복합재료의 가교구조의 증가 때문이라 판단된다.

Keywords: vapor grown carbon nanofibers; epoxy resin; thermal and mechanical properties; crosslinking structure; mechanical interlocking

References
  • 1. Donnet JB, Bansal RCCarbon Fibers, 2nd Ed., Marcel Dekker, New York (1990)
  •  
  • 2. Fitzer ECarbon Fibers and Their Composites, McGraw-Hill, New York (1992)
  •  
  • 3. Kuttel OM, Groening O, Emmenegger C, Schlapbach L, Appl. Phys. Lett., 73, 2113 (1998)
  •  
  • 4. Endo M, Kim YA, Ezaka M, Osada K, Yanagisawa T, Hayashi T, Terrones M, Dresselhaus MS, Nano Lett., 3, 723 (2003)
  •  
  • 5. Seo MK, Park SJ, Chem. Phys. Lett., 44, 395 (2004)
  •  
  • 6. Lakshminarayanan PV, Toghiani H, Pittman CU, Carbon, 42, 2433 (2004)
  •  
  • 7. Oberlin A, Endo M, J. Cryst. Growth, 32, 335 (1976)
  •  
  • 8. Tibbetts GG, Appl. Phys. Lett., 42, 666 (1983)
  •  
  • 9. Benissad F, Gadelle P, Coulon M, Bonntain L, Carbon, 26, 61 (1988)
  •  
  • 10. Arenillas A, Cuervo S, Dominguez A, Menendez JA, Rubiera F, Parra JB, Merino C, Pis JJ, Thermochim. Acta, 423(1-2), 99 (2004)
  •  
  • 11. Patton RD, Pittman CU, Wang L, Hill JR, Composites A, 30, 1081 (1999)
  •  
  • 12. Seo MK, Park SJ, Lee SK, J. Colloid Interface Sci., 285, 306 (2005)
  •  
  • 13. Endo M, Kim YA, Hayashi T, Nishimura K, Matusita T, Miyashita K, Dresselhaus MS, Carbon, 39, 1287 (2001)
  •  
  • 14. Wu GM, Mater. Chem. Phys., 85, 81 (2004)
  •  
  • 15. Wu X, Wang Z, Chen L, Huang X, Carbon, 42, 1965 (2004)
  •  
  • 16. Muhl T, Kretz J, Monch I, Schneider CM, Bruckl H, Reiss G, Appl. Phys. Lett., 76, 786 (2000)
  •  
  • 17. Giltrow JP, Lancaster JK, Wear, 12, 91 (1968)
  •  
  • 18. Giltrow JP, Lancaster JK, Wear, 16, 359 (1970)
  •  
  • 19. Bauer RSEpoxy Resins Chemistry, American Chemical Society, Washington DC (1979)
  •  
  • 20. May CAEpoxy Resins, Marcel Pekker, New York (1988)
  •  
  • 21. Kumar S, Doshi H, Srinivasarao M, Park JO, Schiraldi DA, Polymer, 43(5), 1701 (2002)
  •  
  • 22. Liu W, Hoa SV, Pugh M, Compos. Sci. Technol., 65, 307 (2005)
  •  
  • 23. Mathisen RJ, Yoo JK, Sung CSP, Macromolecules, 20, 1414 (1987)
  •  
  • 24. Park SJ, Jun BR, J. Colloid Interface Sci., 284(1), 204 (2005)
  •  
  • 25. Park SJ, Seo DI, Lee JR, Kim DS, Polym.(Korea), 25(4), 587 (2001)
  •  
  • 26. Park SJ, Jang YS, J. Colloid Interface Sci., 263(1), 170 (2003)
  •  
  • 27. Friedrich KFriction and Wear of Polymer Composites, Elsevier, New York (1986)
  •  
  • 28. Sin HC, Saka N, Suh NP, Wear, 55, 163 (1979)
  •  
  • 29. Gmbel LFriction and Lubrication in Mechanical Engineering, Krayn, Berlin (1925)
  •  
  • Polymer(Korea) 폴리머
  • Frequency : Bimonthly(odd)
    ISSN 0379-153X(Print)
    ISSN 2234-8077(Online)
    Abbr. Polym. Korea
  • 2024 Impact Factor : 0.6
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This Article

  • 2005; 29(5): 481-485

    Published online Sep 25, 2005

  • Received on Jun 16, 2005
  • Accepted on Sep 5, 2005