• Correlation between Physico-Mechanical and Rheological Properties of Rubber Compounds Based on NR-BR with C-C Gel Content in Polybutadiene
  • Ganjali ST, Motiee F, Tabatabaie ZG
  • NR-BR 기반 고무소재에서 폴리부타디엔의 C-C 겔 함량과 물리기계적, 유변학적 특성 사이의 상호관계
Abstract
In this study, microstructure and gel content (C-C) of polybutadiene rubber (PBR) were investigated using various techniques including ASTM D 3616, attenuated total reflectance Fourier transform infrared spectrometry (ATR FTIR), differential scanning calorimetry (DSC) and nuclear magnetic resonance spectroscopy (NMR). The ATR FTIR spectra of the samples were investigated to determine the cis, trans, 1, 2-vinyl and the C-C gel content in PBR. The absorbance ratios of specific peaks in different grades of PBR were correlated with the C-C gel content measured by the ATR FTIR techniques. Physico-mechanical and rheological properties of rubber compounds based on BR with various amounts of gel were determined. The results showed that there is an acceptable correlation between these properties and the C-C gel content of PBR.

Keywords: polybutadiene rubber; C-C gel content; ATR FTIR; physico-mechanical and rheological properties; NR/BR blend.

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This Article

  • 2014; 38(4): 425-433

    Published online Jul 25, 2014

  • Received on Nov 19, 2013
  • Accepted on Feb 13, 2014