• Swelling Properties, Compression Set Behavior and Abrasion Resistance of Ethylene-propylene-diene Rubber/Styrene Butadiene Rubber Blend Nanocomposites
  • Vishvanathperumal S, Gopalakannan S
  • Nanoclay를 이용한 EPDM/SBR 블렌드 나노복합재료의 팽윤 및 압축변형, 마모저항 특성
Abstract
The ethylene-propylene-diene monomer (EPDM)/styrene-butadiene rubber (SBR)/nanoclay (NC) nanocomposites were prepared with various nanoclay contents loading and different crosslinking systems by using an open mill mixer. Sulfur, dicumyl peroxide and the mixed system were used as crosslinking systems for the nanocomposites. The effects of nanoclay loading and crosslinking systems on the swelling behavior, compression set behavior, abrasion resistance, hardness, rebound resilience and water uptake of EPDM/SBR blends were investigated. Mole percent uptake of aromatic, aliphatic and chlorinated hydrocarbons through the nanocomposites was investigated at 23 °C. The peroxide cured nanocomposites have exhibited the lowest solvent uptake in all the penetrant as well as the lowest uptake exhibited by aliphatic hydrocarbons. An increase in nanoclay loading resulted in reduction in water uptake and rebound resilience as well as increases in compression set, hardness, and abrasion resistance in all the crosslinking systems.

Keywords: EPDM/SBR blends; nanoclay loading; crosslinking systems; nanocomposites

References
  • 1. Hess WM, Vegvari PC, Swor RA, Rubber Chem. Technol., 58, 350 (1985)
  •  
  • 2. Szazdi L, Pozsgay A, Pukanszky B, Eur. Polym. J., 43, 345 (2007)
  •  
  • 3. LeBaron PC, Wang Z, Pinnavaia TJ, Appl. Clay Sci., 15, 11 (1999)
  •  
  • 4. Goettler LA, Lee KY, Thakkar H, Polym. Rev., 47, 291 (2007)
  •  
  • 5. Arroyo M, Lopez-Manchado MA, Herrero B, Polymer, 44(8), 2447 (2003)
  •  
  • 6. Carretero-Gonzalez J, Verdejo R, Toki S, Hsiao BS, Giannelis EP, Lopez-Manchado MA, Macromolecules, 41(7), 2295 (2008)
  •  
  • 7. Al-Yamani F, Goettler LA, Rubber Chem. Technol., 80, 100 (2007)
  •  
  • 8. Munusamy Y, Ismail H, Mariatti M, Ratnam CT, J. Reinf. Plast. Compos., 27, 1925 (2008)
  •  
  • 9. Zhang ZJ, Zhang LN, Li Y, Xu HD, Polymer, 46(1), 129 (2005)
  •  
  • 10. Yoon JT, Jo WH, Lee MS, Ko MB, Polymer, 42(1), 329 (2001)
  •  
  • 11. Ha SR, Ryu SH, Park SJ, Rhee KY, Mater. Sci. Eng. A-Struct. Mater. Prop. Microstruct. Process., 448, 264 (2007)
  •  
  • 12. Arroyo M, Lopez-Manchado MA, Valentin JL, Carretero J, Compos. Sci. Technol., 67, 1330 (2007)
  •  
  • 13. Ahmadi SJ, Huang Y, Li W, Compos. Sci. Technol., 65, 1069 (2005)
  •  
  • 14. Wu YP, Wang YQ, Zhang HF, Wang YZ, Yu DS, Zhang LQ, Yang J, Compos. Sci. Technol., 65, 1195 (2005)
  •  
  • 15. Hwang WG, Wei KH, Wu CM, Polymer, 45(16), 5729 (2004)
  •  
  • 16. Apostolo M, Triulzi F, J. Fluor. Chem., 125, 303 (2004)
  •  
  • 17. Kim WH, Kim SK, Kang JH, Choe YS, Chang YW, Macromol. Res., 14(2), 187 (2006)
  •  
  • 18. Mathai AE, Singh RP, Thomas S, Polym. Eng. Sci., 43(3), 704 (2003)
  •  
  • 19. Mostafa A, Abouel-Kasem A, Bayoumi MR, El-Sebaie MG, Mater. Des., 30, 1561 (2009)
  •  
  • 20. Rajasekar R, Pal K, Heinrich G, Das A, Das CK, Mater. Des., 30, 3839 (2009)
  •  
  • 21. Nabil AN, Hundiwale DG, Kapadi UR, Mishra S, Polym. -Plast. Technol. Eng., 44, 1159 (2005)
  •  
  • 22. Chew MYL, Zhou X, Polym. Test, 21, 187 (2002)
  •  
  • 23. Kojima M, Tosaka M, Funami E, Nitta K, Ohshima M, Kohjiya S, J. Supercrit. Fluids, 35(3), 175 (2005)
  •  
  • 24. Anil Kumar PV, Ph.D. Thesis, Mahatma Gandhi University, Kerala, India, March 2012.
  •  
  • 25. Gillen KT, Celina M, Bernstein R, Polym. Degrad. Stabil., 82, 25 (2003)
  •  
  • 26. Dannenberg EM, Ind. Eng. Chem., 40, 2199 (1948)
  •  
  • 27. Boonstra BBST, Dannenberg EM, Rubber Age, 82, 838 (1958)
  •  
  • 28. Waksman LS, Schneider NS, Sung NH, Barrier Polymers and structures, Am. Chem. Soc. Symp. Ser. 423, Koros WJ Ed., Washington, Chap.20 (1990).
  •  
  • 29. Southern EM, Thomas AG, Trans. Faraday Soc., 63, 1913 (1967)
  •  
  • 30. Southern E, Thomas AG, J. Polym. Sci. A: Polym. Chem., 3, 46 (1965)
  •  
  • 31. Lawandy SN, Helaly FH, J. Appl. Polym. Sci., 32, 5279 (1986)
  •  
  • 32. Stickney PB, Mueller WJ, Rubber Chem. Technol., 42, 604 (1969)
  •  
  • 33. Aminabhavi TM, Harogoppad SB, J. Chem. Educ., 68, 343 (1991)
  •  
  • 34. Aithal US, Aminabhavi TM, Polymer, 31, 1757 (1990)
  •  
  • 35. Aithal US, Aminabhavi TM, J. Chem. Educ., 67, 82 (1990)
  •  
  • 36. Aminabhavi TM, Balundgi RH, Cassidy PE, Polym. -Plast. Technol. Eng., 29, 235 (1990)
  •  
  • 37. Unnikrishnan G, Thomas S, Polymer, 39(17), 3933 (1998)
  •  
  • 38. George SC, Thomas S, Ninan KN, Polymer, 37(26), 5839 (1996)
  •  
  • 39. van der Schuur M, Gaymans RJ, Polymer, 46(18), 6862 (2005)
  •  
  • 40. Arrighi V, Gagliardi S, Higgins JS, Triolo A, Zanotti JM, Quasielastic neutron scattering as a probe of molecular motion in polymer-filler systems, E-MRS Spring Meeting, N-15, Strasbourg, France, 2002.
  •  
  • 41. Persello J, Designing nanostructured particular fillers for elastomers. Role of nanostructure and polymer filler interactions in rubber reinforcement, E-MRS Spring Meeting, N-8, Strasbourg, France, 2002.
  •  
  • 42. Zaborski M, Donnet JB, Macromol. Symp., 194, 87 (2003)
  •  
  • 43. Durandish M, Alipour A, Chin. J. Polym. Sci., 31, 660 (2013)
  •  
  • 44. Alipour A, Naderi G, Bakhshandeh GR, Vali H, Shokoohi S, Int. Polym. Process., 26(1), 48 (2011)
  •  
  • 45. Sae-oui P, Rakdee C, Thanmathorn P, J. Appl. Polym. Sci., 83(11), 2485 (2002)
  •  
  • 46. Biswas M, Ray SS, Polymer, 39(25), 6423 (1998)
  •  
  • 47. Lopez-Manchado MA, Herrero B, Arroyo M, Polym. Int., 53, 1766 (2004)
  •  
  • 48. Bala P, Samantaray BK, Srivastava SK, Nando GB, J. Appl. Polym. Sci., 92(6), 3583 (2004)
  •  
  • 49. Varghese S, Gatos KG, Apostolov AA, Karger-Kocsis J, J. Appl. Polym. Sci., 92(1), 543 (2004)
  •  
  • 50. Wu YP, Jia QX, Yu DS, Zhang LQ, J. Appl. Polym. Sci., 89(14), 3855 (2003)
  •  
  • 51. Arayapranee W, Rempel GL, J. Appl. Polym. Sci., 109(2), 932 (2008)
  •  
  • 52. Jacques JE, Rubber compounding, rubber technology and manufacture, 2nd ed., Blow CM, Hepburn C, Butterworths, UK, p 386 (1985).
  •  
  • Polymer(Korea) 폴리머
  • Frequency : Bimonthly(odd)
    ISSN 0379-153X(Print)
    ISSN 2234-8077(Online)
    Abbr. Polym. Korea
  • 2024 Impact Factor : 0.6
  • Indexed in SCIE

This Article

  • 2017; 41(3): 433-442

    Published online May 25, 2017

  • 10.7317/pk.2017.41.3.433
  • Received on Oct 7, 2016
  • Accepted on Nov 28, 2016