Article
  • Adjusting Water Absorption, Stimulus-Response and Adsorption Capacity for Toxic Heavy Metal Ions of Poly(acrylamide-co-potassium methacrylate) Hydrogel by Poly(ethylene glycol) Addition
  • Syed Wasim Ali , Munib Ahmed Shafique*, Muhammad Arif Malik**, Muhammad Saad, Syeda Rida Amber***, and Aatiqa Jabeen****

  • Chemistry Division, Pakistan Institute of Nuclear Science and Technology (PINSTECH), PO 45650, Nilore, Islamabad, Pakistan
    *Central Analytical Facility Division, Pakistan Institute of Nuclear Science and Technology (PINSTECH), PO 45650, Nilore, Islamabad, Pakistan
    **Department of Chemistry and Biochemistry, Hampton University, Hampton, VA 23668, USA
    ***Chemistry Department, University of Wah, Quaid Avenue, PO 47040, Wah Cantt, Pakistan
    ****Department of Chemistry, Quaid-i-Azam University, Islamabad 45320, Pakistan

  • Poly(ethylene glycol) 첨가에 따른 Poly(acrylamide-co-potassium methacrylate) 하이드로젤의 독성 중금속 이온에 대한 수분흡수, 자극반응 및 흡착 능력 조절
  • Reproduction, stored in a retrieval system, or transmitted in any form of any part of this publication is permitted only by written permission from the Polymer Society of Korea.

References
  • 1. Singha, N. R.; Dutta, A.; Mahapatra, M.; Roy, J. S. B.; Mitra, M.; Deb, M.; Chattopadhyay, P. K. In Situ Attachment of Acrylamido Sulfonic Acid-Based Monomer in Terpolymer Hydrogel Optimized by Response Surface Methodology for Individual and/or Simultaneous Removal(s) of M(III) and Cationic Dyes. ACS Omega 2019,4, 1763-1780.
  •  
  • 2. TaŞar, Ş.; Orhan, R. Temperature-responsive Poly(acrylamide-co-N-isopropyl acrylamide) Hydrogels: Synthesis, Characterization and Sorption Application. Polym. Korea 2020, 44, 49-60.
  •  
  • 3. İnam, R.; Çaykara, T.; Kantoĝlu, Ö. Polographic Determination of Uranyl Adsorption onto Poly(acrylamide-g-ethylenediamine- tetraacetic acid) Hydrogels in the Presence of Cadmium and Lead. Nucl. Instrum. Methods Phys. Res. Sect. B 2003, 208, 400-404.
  •  
  • 4. Wongjaikham, W.; Wongsawaeng, D.; Hosemann, P. Synthesis of Amidoxime Polymer Gel to Extract Uranium Compound from Seawater by UV Radiation Curing. J. Nucl. Sci. Technol. 2019, 56, 541-552.
  •  
  • 5. Çaykara, T.; İnam, R.; Özyürek, C. Radiation Synthesis and Uranyl Ion Adsorption of Poly(2-hydroxyethyl methacrylate/maleic acid) Hydrogels. J. Polym. Sci. A Polym. Chem. 2001, 39, 277-283.
  •  
  • 6. Angar, N.-E.; Aliouche, D. An Enhanced Immobilization of BSA Biomolecule on Anionic Hydrogels: Swelling and Adsorption Modelling. Chem. Pap. 2017, 71, 1389-1397.
  •  
  • 7. Bajpai, S. K.; Dubey, S. In Vitro Dissolution Studies for Release of Vitamin B12 from Poly(N-vinyl-2-pyrrolidone-co-acrylic acid) Hydrogels. React. Funct. Polym. 2005, 62, 93-104.
  •  
  • 8. Heidari, S.; Esmaeilzadeh, F.; Mowla, D.; Ghasemi, S. Synthesis of an Efficient Copolymer of Acrylamide and Acrylic Acid and Determination of its Swelling Behaviour. J. Pet. Explor. Prod. Technol. 2018, 8, 1331-1340.
  •  
  • 9. Saraydɪn, D.; Ișɪkver, Y.; Karadaǧ, E. Adsorption of Phenazine Dyes Using Poly(Hydroxamic Acid) Hydrogels from Aqueous Solutions. Polym. Eng. Sci. 2018, 58, 310-318.
  •  
  • 10. Oucif, A.; Haddadine, N.; Zakia, D.; Bouslah, N.; Benaboura, A.; Beyaz, K.; Guedouar, B.; El-Shall, M. S. Poly(hydroxyethyl methacrylate-co-hydroxyethyl acrylate) Soft Contact Lenses for Acetazolamide Release. Polym. Bull. [Online early access]. DOI: 10.1007/s00289-021-03573-5. Published Online: Feb 8, 2021 (accessed Feb 8, 2021).
  •  
  • 11. Yuan, D.; Jacquier, J. C.; O’Riordan, E. D. Entrapment of Proteins and Peptides in Chitosan-Polyphosphoric Acid Hydrogel Beads: A New Approach to Achieve Both High Entrapment Efficiency and Controlled In Vitro Release. Food Chem. 2018, 239, 1200-1209.
  •  
  • 12. Tay, J.-W.; Choe, D.-H.; Mulchandani, A.; Rust, M. K. Hydrogels: From Controlled Release to a New Bait Delivery for Insect Pest Management. J. Econ. Entom. 2020, 113, 2061-2068.
  •  
  • 13. Ali, S. W.; Zaidi, S. A. R. Synthesis of Copolymeric Acrylamide/Potassium Acrylate Hydrogels Blended with Poly(Vinyl Alcohol): Effect of Crosslinking and the Amount of Poly(Vinyl Alcohol) on Swelling Behaviour. J. Appl. Polym. Sci. 2005, 98, 1927-1931.
  •  
  • 14. Omidian, H.; Hashemi, S. A.; Askari, F.; Nafisi, S. Swelling and Crosslink Density Measurements for Hydrogels. Iranian J. Polym. Sci. Technol. 1994, 3, 115-119.
  •  
  • 15. Khare, A. R.; Peppas, N. A. Swelling/deswelling of Anionic Copolymer Gels. Biomaterials 1995, 16, 559-567.
  •  
  • 16. Castel, D.; Ricard, A.; Audebert, R. Swelling of Anionic and Cationic Starch‐Based Superabsorbents in Water and Saline Solution. J. Appl. Polym. Sci. 1990, 39, 11-29.
  •  
  • 17. Hosseinzadeh, H.; Alijani, D. Synthesis, Characterization and Swelling Properties of Chitosan/Poly(acrylic acid-co-crotonic acid) Semi-Interpenetrating Polymer Networks. Polym. Korea 2014, 38, 588-595.
  •  
  • 18. Mahdavinia, G. R.; Pourjavadi, A.; Hosseinzadeh, H.; Zahuriaan, M. J. Modified Chitosan 4. Superabsorbent Hydrogels from Poly(acrylic acid-co-acrylamide) Grafted Chitosan with Salt-and pH-Responsiveness Properties, Eur. Polym. J. 2004, 40, 1399-1407.
  •  
  • 19. Liu, Y.; Cao, X.; Hua, R.; Wang, Y.; Liu, Y.; Pang, C.; Wang, Y. Selective Adsorption of Uranyl Ion on Ion-Imprinted Chiatosan/PVA Cross-Linked Hydrogel. Hydrometallurgy 2010, 104, 150-155.
  •  
  • 20. Ali, A. EI-H.; Shawky, H. A.; El-Rehim, H. A. A.; Hegazy, E. A. Synthesis and Characterization of PVA/AAC Copolymer Hydrogel and its Applications in the Removal of Heavy Metals from Aqueous Solution. Eur. Polym. J. 2003, 39, 2337-2344.
  •  
  • 21. Akkaya, R.; Ulusoy, U. Adsorptive Features of Chitosan Entrapped in Polyacrylamide Hydrogel for Pb2+, UO22+, and Th4+. J. Hazard. Mater. 2008, 151, 380-388.
  •  
  • 22. Kam, E.; Taşdelen, B.; Osmanlioglu, A. E. Uranyl Ion Uptake Capacity of Poly(isopropylacrylamide/malic Acid) Copolymeric Hydrogels Prepared by Gamma Rays. Radiat. Phys. Chem. 2012, 81, 618-621.
  •  
  • 23. CRC Handbook of Chemistry and Physics, 69th Edition; Weast, R. C., Ed.: CRC Press Inc.: Boca Rosa, 1988.
  •  
  • 24. Hennink, W. E.; Van Nostrum, C. F. Novel Crosslinking Methods to Design Hydrogels. Adv. Drug. Deliv. Rev. 2002, 54, 13-36.
  •  
  • 25. Guilherme, M. R.; Aouada, F. A.; Fajardo, A. R.; Martins, A. F.; Paulino, A. T.; Davi, M. F. T.; Rubira, A. F.; Muniz, E. C. Super- absorbent Hydrogels Based on Polysaccharides for Application in Agriculture as Soil Conditioner and Nutrient Carrier: A Review. Eur. Polym. J. 2015, 72, 365-385.
  •  
  • 26. Rička, J.; Tanaka, T. Swelling of Ionic Gels: Quantitative Performance of the Donnan Theory. Macromolecules 1984, 17, 2916-2921.
  •  
  • 27. Zhou, X.; Weng, L.; Chen, Q.; Zhang, J.; Shen, D.; Li, Z.; Shao, M.; Xu, J. Investigation of pH Sensitivity of Poly(acrylicacid‐ co‐acrylamide) Hydrogel. Polym. Int.2003, 52, 1153-1157.
  •  
  • 28. Kiatkamjornwong, S.; Mongkolsawat, K.; Sonsuk, M. Synthesis and Property Characterization of Cassava Starch Grafted Poly [acrylamide-co-(maleic acid)] Superabsorbent via g-Irradiation. Polymer 2002, 43, 3915-3924.
  •  
  • 29. Ion exchangers; Dorfner, K. Ed.: Walter de Gruyter: New York, 1991.
  •  
  • Polymer(Korea) 폴리머
  • Frequency : Bimonthly(odd)
    ISSN 0379-153X(Print)
    ISSN 2234-8077(Online)
    Abbr. Polym. Korea
  • 2022 Impact Factor : 0.4
  • Indexed in SCIE

This Article

  • 2021; 45(6): 832-840

    Published online Nov 30, -0001

  • 10.7317/pk.2021.45.6.832
  • Received on Nov 30, -0001
  • Revised on Nov 30, -0001
  • Accepted on Nov 30, -0001

Correspondence to

  • Syed Wasim Ali
  • Chemistry Division, Pakistan Institute of Nuclear Science and Technology (PINSTECH), PO 45650, Nilore, Islamabad, Pakistan

  • E-mail: swasimali@pinstech.org.pk