Article
  • In situ Copolymerized Toughened Polymethyl Methacrylate (PMMA) with Highly Transparency for Support Film of Polarizers

  • Yingying Wang*, Bin Yang*, **,† , Liangyong He*, Yuqing Yang*, Nuo Zhang*, Yang Wang*, Zhiqiang Shi*, **, Yuchao Ke**, Lifen Su***, Jiasheng Qian*, Ru Xia*, and Tao Jiang****

  • *College of Chemistry & Chemical Engineering, Key Laboratory of Environment-Friendly Polymeric Materials of Anhui Province, Anhui University, Hefei 230601, Anhui, P.R. China
    **Anhui Zhongding Sealing Parts Co., Ltd., Ningguo 242399, Anhui, P.R. China
    ***School of Materials Science & Engineering, Anhui University, Hefei 230601, Anhui, P.R. China
    ****Longteng Security & Surveillance Technology Co, Ltd., Lu’an 237001, Anhui, P.R. China

  • 편광자 지지체를 위한 투명도가 높은 Insitu 공중합 강화 PMMA 고분자

  • Reproduction, stored in a retrieval system, or transmitted in any form of any part of this publication is permitted only by written permission from the Polymer Society of Korea.

References
  • 1. Huang, Y.; Zhang, X.; Li, C.; Zhao, Y.; Zhang, Y. H.; Qu, J. Atmospheric Persistence and Toxicity Evolution for Fluorinated Biphenylethyne Liquid Crystal Monomers Unveiled by In silico Methods. J. Hazard. Mater. 2022, 424, 127519.
  •  
  • 2. Wang, Y.; Wang, R.; Zhang, C.; Wang, J. Full Components Recovery of Organic Matter and Indium from Discarded Liquid Crystal Display Panels. J. Cleaner Prod. 2021, 299, 126862.
  •  
  • 3. Ma, J.; Ye, X.; Jin, B. Structure and Application of Polarizer Film for Thin-film-transistor Liquid Crystal Displays. Displays 2011, 32, 49-57.
  •  
  • 4. Wu, C. L.; Yao, P. H.; Lin, C. H.; Sung, C. K.; Chen, C. H. Fabrication of Flexible Metallic Wire Grid Polarizer Using Thermal NIL and Lift-off Processes. Microelectron. Eng. 2012, 98, 117-120.
  •  
  • 5. Park, E. J.; Kim, I. S.; Park, S. S.; Lee, H. S.; Lee, M. S. Miscibility of Melt-mixed PLLA/PMMA Blends for Optical Film Application. Polym. Korea 2013, 37, 744-752.
  •  
  • 6. Kim, H. J.; Kim, D. W.; Kim, S. W. Improvement of Optical and Thermo-mechanical Properties of Polycarbonate-based Diffusers for LED Backlight Unit by Incorporation of Porous Silica Particles. Polym. Korea 2013, 36, 761-767.
  •  
  • 7. Han, K. H.; Kim, W. N.; Kim, J. Effect of Immiscible Polymer in Improving the Reflectivity and Productivity of Polymer Blending Film Containing Polyethylene Terephthalate. Polym. Korea 2021, 45, 363-371.
  •  
  • 8. Song, D. G.; Lee, J.; Choi, H. J.; Kim, J. K. Study on Contact Lens That Blocks Blue Light from LED. Polym. Korea 2022, 46, 62-67.
  •  
  • 9. Zhang, Y.; Zhuang, S.; Xu, X.; Hu, J. Transparent and UV-shielding ZnO@PMMA Nanocomposite Films. Opt. Mater. 2013, 36, 169-172.
  •  
  • 10. Tran, T. N.; Paul, U.; Heredia Guerrero, J. A.; Liakos, I.; Marras, S.; Scarpellini, A.; Ayadi, F.; Athanassiou, A.; Bayer, I. S. Transparent and Flexible Amorphous Cellulose-acrylic Hybrids. Chem. Eng. J. 2016, 287, 196-204.
  •  
  • 11. Xu, J.; Li, D. Preparation and Photoluminescence of Transparent Poly(methyl methacrylate)-based Nanocomposite Films with Ultra-high-loading Pendant ZnS Quantum Dots. Polymers (Basel) 2018, 10, 1217.
  •  
  • 12. Martín-de León, J.; Jiménez, M.; Pura, J. L.; Bernardo, V.; Rodriguez-Pérez, M. A. Easy-way Production of Highly Transparent Nanocellular Polymers Films. Polymer 2021, 236, 124298.
  •  
  • 13. Wie, J.; Kim, J. Thermal Conductivity Enhancement Derived from Poly(Methyl Methacrylate)-grafted Carbon Nanotubes in Poly(methyl methacrylate)/polystyrene Blends. Polymers (Basel) 2019, 11, 1347.
  •  
  • 14. Wang, Y.; Liu, P.; Wang, H.; Zeng, B.; Wang, J.; Chi, F. Flexible Organic Light-emitting Devices with Copper Nanowire Composite Transparent Conductive Electrode. J. Mater. Sci. 2018, 54, 2343-2350.
  •  
  • 15. Hamlaoui, F. Z.; Naar, N. Improvement of the Structural and Electrical Properties of PMMA/PANI-MA Blends Synthesized by Interfacial In situ Polymerization in a Continuous Organic Phase. Polym. Bull. 2020, 79, 37-63.
  •  
  • 16. Jamaluddin, N.; Hsu, Y. I.; Asoh, T. A.; Uyama, H. Optically Transparent and Toughened Poly(methyl methacrylate) Composite Films with Acylated Cellulose Nanofibers. ACS Omega 2021, 6, 10752-10758.
  •  
  • 17. Mao, Z.; Jiang, T.; Zhang, X.; Jiang, G.; Zhang, J. Co-continuous Phase Structure Formed in Melt Processing Inducing Shear Bands to Prevent Crack Propagation: Significant Improvement in Impact Toughness of PMMA. Polym. Test. 2020, 85, 106425.
  •  
  • 18. Büyükkaya, K.; Demirer, H. Examining the Mechanical and Thermomechanical Properties of Polymethylmethacrylate Composites Reinforced with Nettle Fibres. Arabian J. Sci. Eng. 2019, 45, 665-674.
  •  
  • 19. Xia, J.; Luo, X.; Huang, J.; Ma, J.; Yang, J. Preparation of Core/Shell Organic–inorganic Hybrid Polymer Nanoparticles and Their Application to Toughening Poly(methyl methacrylate). RSC Adv. 2021, 11, 34036-34047.
  •  
  • 20. Zheng, J.; Wang, L.; Hu, Y.; Yao, K. Toughening Effect of Comonomer on Acrylic Denture Base Resin Prepared via Suspension Copolymerization. J. Appl. Polym. Sci. 2012, 123, 2406-2413.
  •  
  • 21. Ye, F.; Chen, S.; Tang, G.; Ma, M.; Wang, X. Self-assembled Nanofibrillar Gel Network Toughened PMMA Nanocomposite by In situ Thermal Polymerization of MMA Gel. Colloids Surf., A 2015, 480, 1-10.
  •  
  • 22. Kubiak, J. M.; Yan, J.; Pietrasik, J.; Matyjaszewski, K. Toughening PMMA with Fillers Containing Polymer Brushes Synthesized via Atom Transfer Radical Polymerization (ATRP). Polymer 2017, 117, 48-53.
  •  
  • 23. Monsores, K. G. d. C.; Silva, A. O. d.; Oliveira, S. d. S. A.; Rodrigues, J. G. P.; Weber, R. P. Influence of Ultraviolet Radiation on Polymethylmethacrylate (PMMA). J. Mater. Res. Technol. 2019, 8, 3713-3718.
  •  
  • 24. Rodič, P.; Lekka, M.; Andreatta, F.; Fedrizzi, L.; Milošev, I. The Effect of Copolymerisation on the Performance of Acrylate-based Hybrid Sol-gel Coating for Corrosion Protection of AA2024-T3. Prog. Org. Coat. 2020, 147, 105701.
  •  
  • 25. Krishnan, M. R.; Aldawsari, Y. F.; Alsharaeh, E. H. Three‐ dimensionally Cross‐linked Styrene‐methyl Methacrylate‐divinyl Benzene Terpolymer Networks for Organic Solvents and Crude Oil Absorption. J. Appl. Polym. Sci. 2020 138, 49942.
  •  
  • 26. Suresh, S. S.; Mohanty, S.; Nayak, S. K. Preparation and Characterization of Recycled Blends Using Poly(vinyl chloride) and Poly(methyl methacrylate) Recovered from Waste Electrical and Electronic Equipments. J. Cleaner Prod. 2017, 149, 863-873.
  •  
  • 27. Fu, Q.; Lin, G.; Chen, X.; Yu, Z.; Yang, R.; Li, M.; Zeng, X.; Chen, J. Mechanically Reinforced PVDF/PMMA/SiO2 Composite Membrane and Its Electrochemical Properties as a Separator in Lithium-ion Batteries. Energy Technol. 2018, 6, 144-152.
  •  
  • 28. El Sayed, A. M. Synthesis, Optical, Thermal, Electric Properties and Impedance Spectroscopy Studies on P(VC-MMA) of Optimized Thickness and Reinforced with MWCNTs. Results Phys. 2020, 17, 103025.
  •  
  • 29. Joseph, J.; Deshmukh, K.; Chidambaram, K.; Faisal, M.; Selvarajan, E.; Sadasivuni, K. K.; Ahamed, M. B.; Pasha, S. K. K. Dielectric and Electromagnetic Interference Shielding Properties of Germanium Dioxide Nanoparticle Reinforced Poly(vinyl chloride) and Poly(methylmethacrylate) Blend Nanocomposites. J. Mater. Sci.: Mater. Electron. 2018, 29, 20172-20188.
  •  
  • 30. Arunkumar, R.; Babu, R. S.; Usha Rani, M.; Kalainathan, S. Effect of PBMA on PVC-based Polymer Blend Electrolytes. J. Appl. Polym. Sci. 2017, 134, 44939.
  •  
  • 31. Le, N. X. T.; Trinh, K. T. L.; Lee, N. Y. Poly(acrylic acid) as an Adhesion Promoter for UV-assisted Thermoplastic Bonding: Application for the In vitro Construction of Human Blood Vessels. Mater. Sci. Eng., C 2021,122, 111874.
  •  
  • 32. He, Z.; Zhao, J.; Li, F.; Zhang, D.; Guo, F.; Guo, H.; Wang, X.; Hu, H. In situ Synthesis of Polymer-modified Boron Nitride Nanosheets via Anionic Polymerization. Appl. Surf. Sci. 2021, 537, 147966.
  •  
  • 33. Skandalis, A.; Pispas, S. PLMA-b-POEGMA Amphiphilic Block Copolymers: Synthesis and Self-assembly in Aqueous Media. J. Polym. Sci., Part A: Polym. Chem. 2017, 55, 155-163.
  •  
  • 34. Bagheri, S.; Kalantari, M.; Fozooni, S.; Hashemipour Rafsanjani, H. Synthesis of Organic‐inorganic Hybrid Nanocomposites Based on the Acrylate Monomers and Investigation of Scratch Resistance of These Nanocomposites. Polym. Compos. 2019, 41, 142-160.
  •  
  • 35. Lyoo, W. S.; Seo, I. S.; Yeum, J. H.; Yoon, W. S.; Ji, B. C.; Kim, B. S.; Lee, S. S.; Kim, B. C. Effect of Degree of Saponification on the Rheological Properties of Syndiotactic Poly(vinyl alcohol)/Water Solution. J. Appl. Polym. Sci. 2002, 86, 463-467.
  •  
  • 36. Lyoo, W. S.; Yeum, J. H.; Kwon, O. W.; Shin, D. S.; Han, S. S.; Kim, B. C.; Jeon, H. Y.; Noh, S. K. Rheological Properties of High Molecular Weight (HMW) Syndiotactic Poly(vinyl alcohol) (PVA)/HMW Atactic PVA Blend Solutions. J. Appl. Polym. Sci. 2006, 102, 3934-3939.
  •  
  • 37. Vildanova, R. R.; Sigaeva, N. N.; Kukovinets, O. S.; Kolesov, S. V. Preparation and Rheological Properties of Hydrogels Based on N-succinyl Chitosan and Hyaluronic Acid Dialdehyde. Polym. Test. 2021, 96, 107120.
  •  
  • 38. Ioelovich, M. Adjustment of Hydrophobic Properties of Cellulose Materials. Polymers (Basel) 2021, 13, 1241.
  •  
  • 39. Gao, S. H.; Zhang, G. X.; Zhang, F. X. Surface Modification of Polyester Fibers by Encasing Sucrose Ester and Grafting Soybean Protein. Adv. Mater. Res. 2011, 331, 133-138.
  •  
  • 40. Tateishi, Y.; Kai, N.; Noguchi, H.; Uosaki, K.; Nagamura, T.; Tanaka, K. Local Conformation of Poly(methyl methacrylate) at Nitrogen and Water Interfaces. Polym. Chem. 2010, 1, 303-311.
  •  
  • 41. Lin, Y.; Bilotti, E.; Bastiaansen, C. W. M.; Peijs, T. Transparent Semi‐crystalline Polymeric Materials and Their Nanocomposites: A Review. Polym. Eng. Sci. 2020, 60, 2351-2376.
  •  
  • 42. Saad-Gouider, N.; Estevez, R.; Agnon, C.; Seguela, R. Calibration of a Viscoplastic Cohesive Zone for Crazing in PMMA. Eng. Fract. Mech. 2006, 73, 2503-2522.
  •  
  • 43. Xu, S.; Wang, Z.; Cao, M.; Dai, X.; Zhang, S.; Liu, L. Preparation and Properties of Anionic Nylon-6-b-polyether Amine Copolymers with Varying Soft Chain Length. Polym. Plast. Technol. Eng. 2018, 57, 1430-1439.
  •  
  • 44. Xu, S.; Wang, Z.; Liu, L.; Dai, X.; Zhang, S.; Cao, M. Respective Contribution Research of Soft Component and Macroinitiator on Synthesis and Performance of MCPA-PEA Materials. Polym. Eng. Sci. 2018, 58, 1353-1361.
  •  
  • 45. Lu, Z.; Guan, W.; Tang, L. High Performances Polyurethane-urea Polyacrylate Hybrid Emulsion Coatings with Multiple Crosslinking Structures. Prog. Org. Coat. 2019, 132, 328-335.
  •  
  • 46. Ren, G.; Miao, Y.; Qiao, L.; Qin, Y.; Wang, X.; Wang, F. Toughening of Amorphous Poly(propylene carbonate) by Rubbery CO2-based Polyurethane: Transition from Brittle to Ductile. RSC Adv. 2015, 5, 49979-49986.
  •  
  • 47. Zhu, Y. P.; Wang, L. S.; Zhang, A. Q.; Wang, X.; Cai, T.; Zeng, X. Toughening Effect of Poly(ethene-co-1-butene)-graft-methyl Methacrylate and Acrylonitrile on Styrene-acrylonitrile Copolymer (SAN). J. Macromol. Sci., Part B: Phys. 2010, 49, 757-769.
  •  
  • Polymer(Korea) 폴리머
  • Frequency : Bimonthly(odd)
    ISSN 0379-153X(Print)
    ISSN 2234-8077(Online)
    Abbr. Polym. Korea
  • 2022 Impact Factor : 0.4
  • Indexed in SCIE

This Article

  • 2022; 46(5): 566-576

    Published online Sep 25, 2022

  • 10.7317/pk.2022.46.5.566
  • Received on Apr 11, 2022
  • Revised on Jul 1, 2022
  • Accepted on Jul 7, 2022

Correspondence to

  • Bin Yang

  • *College of Chemistry & Chemical Engineering, Key Laboratory of Environment-Friendly Polymeric Materials of Anhui Province, Anhui University, Hefei 230601, Anhui, P.R. China
    **Anhui Zhongding Sealing Parts Co., Ltd., Ningguo 242399, Anhui, P.R. China

  • E-mail: yangbin@ahu.edu.cn