Article
  • Study on the Hybrid Dual-functioning Application of Urethane Foam Modified with Graphene Oxide and Polypyrrole for an Electrode Scaffold as Well as Chemical Sensor

  • Hyeon-Jin Cho, Young-Ju Noh, Eun-Young Jin, and Jin-Heong Yim†

  • Division of Advanced Materials Engineering, Kongju National University, 1223-24 Cheonandaero, Cheonan, Chungnam 31080, Korea

  • 그래핀 옥사이드와 폴리피롤로 개질된 우레탄 폼의 전극 지지체 및 화학 센서로 하이브리드 이중 기능화 연구

  • 조현진 · 노영주 · 진은영 · 임진형†

  • 공주대학교 공과대학 신소재공학부

  • Reproduction, stored in a retrieval system, or transmitted in any form of any part of this publication is permitted only by written permission from the Polymer Society of Korea.

References
  • 1. Su, Y.; Wang, J.; Wang, B.; Yang, T.; Yang, B.; Xie, G.; Zhou, Y.; Zhang, S.; Tai, H.; Cai, Z.; Chen, G.; Jiang, Y.; Chen, L.-Q.; Chen, J. Alveolus-inspired Active Membrane Sensors for Self-powered Wearable Chemical Sensing and Breath Analysis. ACS Nano. 2020, 14, 6067-6075.
  •  
  • 2. Su, Y.; Yang, T.; Zhao, X.; Cai, Z.; Chen, G.; Yao, M.; Chen, K.; Bick, M.; Wang, J.; Li, S.; Xie, G.; Tai, H.; Du, X.; Jiang, Y.; Chen, J. A Wireless Energy Transmission Enabled Wearable Active Acetone Biosensor for Non-invasive Prediabetes Diagnosis. Nano Energy. 2020, 74 104941.
  •  
  • 3. Su, Y.; Xie, G.; Chen, J.; Du, H.; Zhang, H.; Yuan, Z.; Ye, Z.; Du, X.; Tai, H.; Jiang, Y. Reduced Graphene Oxide–polyethylene Oxide Hybrid Films for Toluene Sensing at Room Temperature. RSC Adv. 2016, 6, 97840-97847.
  •  
  • 4. Wen, Z.; Chen, J.; Yeh, M.-H.; Guo, H.; Li, Z. Fan, X.; Zhang, T.; Zhu, L.; Wang, Z. L., Blow-driven Triboelectric Nanogenerator as An Active Alcohol Breath Analyzer. Nano Energy. 2015, 16, 38-46.
  •  
  • 5. He, Y.; Shi, X.; Chen, K.; Yang, X.; Chen, J. Titanium-doped P-Type WO3 Thin Films for Liquefied Petroleum Gas Detection, Nanomaterials. 2020, 10, 727.
  •  
  • 6. Serna-Maza, A.; Heaven, S.; Banks, C. J. Ammonia Removal in Food Waste Anaerobic Digestion Using a Side-stream Stripping Process, Bioresour. Technol. 2014, 152, 307-315.
  •  
  • 7. Health, N. Y. S. D. O. New York State Department of Health the Facts about Ammonia, Facts About Ammon. Tech. Inf. 2004.
  •  
  • 8. Manne, J.; Sukhorukov, O.; Jäger, W.; Tulip, J. Pulsed Quantum Cascade Laser-based Cavity Ring-down Spectroscopy for Ammonia Detection in Breath, Appl. Opt. 2006, 45, 9230.
  •  
  • 9. Ogimoto, Y.; Selyanchyn, R.; Takahara, N.; Wakamatsu, S.; Lee, S.-W. Detection of Ammonia in Human Breath Using Quartz Crystal Microbalance Sensors with Functionalized Mesoporous SiO2 Nanoparticle Films, Sensors Actuators B Chem. 2015, 215, 428-436.
  •  
  • 10. Güntner, A. T.; Righettoni, M.; Pratsinis, S. E. Selective Sensing of NH3 by Si-doped α-MoO3 for Breath Analysis, Sensors Actuators B Chem. 2016, 223, 266-273.
  •  
  • 11. Hibbard, T.; Crowley, K.; Kelly, F.; Ward, F.; Holian, J.; Watson, A.; Killard, A. J. Point of Care Monitoring of Hemodialysis Patients with a Breath Ammonia Measurement Device Based on Printed Polyaniline Nanoparticle Sensors, Anal. Chem. 2013, 85 12158-12165.
  •  
  • 12. Kotani, A.; Wakabayashi, Y.; Kohama, M.; Kusu, F. Determination of Ammonia in Exhaled Breath by Flow Injection Analysis with Electrochemical Detection, Electrochemistry. 2012, 80, 340-344.
  •  
  • 13. Ji, X.; Banks, C. E.; Silvester, D. S.; Aldous, L.; Hardacre, C.; Compton, R. G. Electrochemical Ammonia Gas Sensing in Nonaqueous Systems: a Comparison of Propylene Carbonate with Room Temperature Ionic Liquids, Electroanalysis. 2007, 19, 2194-2201.
  •  
  • 14. Oudenhoven, J. F. M.; Knoben, W.; van Schaijk, R. Electrochemical Detection of Ammonia Using a Thin Ionic Liquid Film as the Electrolyte, Procedia Eng. 2015, 120, 983-986.
  •  
  • 15. Aarya, S;. Kumar, Y.; Chahota, R. K. Recent Advances in Materials, Parameters, Performance and Technology in Ammonia Sensors: a Review, J. Inorg. Organomet. Polym. Mater. 2020, 30, 269-290.
  •  
  • 16. Chen, S.; Sun, G.; High Sensitivity Ammonia Sensor Using a Hierarchical Polyaniline/poly(ethylene-co-glycidyl methacrylate) Nanofibrous Composite Membrane, ACS Appl. Mater. Interfaces. 2013, 5, 6473-6477
  •  
  • 17. Panes-Ruiz, L. A.; Shaygan, M.; Fu, Y.; Liu, Y.; Khavrus, V.; Oswald, S.; Gemming, T.; Baraban, L.; Bezugly, V.; Cuniberti, G. Toward Highly Sensitive and Energy Efficient Ammonia Gas Detection with Modified Single-walled Carbon Nanotubes At Room Temperature, ACS Sens. 2018, 3, 79-86.
  •  
  • 18. Mackin, C.; Schroeder, V.; Zurutuza, A.; Su, C.; Kong, J.; Swager, T. M.; Palacios, T.; Chemiresistive Graphene Sensors for Ammonia Detection, ACS Appl. Mater. Interfaces. 2018, 10, 16169-16176.
  •  
  • 19. Huang, S.; Panes-Ruiz, L. A.; Croy, A.; L¨offler, M.; Khavrus, V., Bezugly, V.; Cuniberti, G. Highly Sensitive Room Temperature Ammonia Gas Sensor Using Pristine Graphene: the Role of Biocompatible Stabilizer, Carbon. 2021, 173, 262-270.
  •  
  • 20. Bezzon, V. D. N.; Montanheiro, T. L. A.; de Menezes, B. R. C.; Ribas, R. G.; Righetti, V. A. N.; Rodrigues, K. F.; Thim, G. P. Carbon Nanostructure-based Sensors: a Brief Review on Recent Advances, Adv. Mater. Sci. Eng. Int. J. 2019, 1-21.
  •  
  • 21. Kour, R.; Arya, S.; Young, S.-J.; Gupta, V.; Bandhoria, P.; Khosla A. Review—recent Advances in Carbon Nanomaterials as Electrochemical Biosensors, J. Electrochem. Soc. 2020, 167, 037555.
  •  
  • 22. Hong,S. Y.; Oh, J. H.; Park, H.; Yun, J. Y.; Jin, S. W.; Sun, L.; Zi, G.; Ha, J. S. Polyurethane Foam Coated with a Multi-walled Carbon Nanotube/polyaniline Nanocomposite for a Skin-like Stretchable Array of Multi-functional Sensors, NPG Asia Mater. 2017, 9, e448.
  •  
  • 23. Ly, T. N.; Park, S. Highly Sensitive Ammonia Sensor for Diagnostic Purpose Using Reduced Graphene Oxide and Conductive Polymer, Sci. Rep. 2018, 8, 18030.
  •  
  • 24. Park, J. S.; Kang, H. J.; Lee, B.-T.; Choi, J. S.; Yim, J.-H. Mechanically and Electricallyenhanced Polyurethane-poly(3,4-ethylenedioxythiophene) Conductive Foams with Aligned Pore Structures Promote MC3T3-E1 Cell Growth and Proliferation, ACS Appl. Polym. Mater. 2020, 2, 1482-1490.
  •  
  • 25. Park, J. S.; Kim, B.; Lee, B.-T.; Choi, J. S.; Yim, J.-H. Fabrication of and Electroconductive, Flexible, and Soft Poly(3,4-ethylenedioxythiophene)–thermoplastic Polyurethane Hybrid Scaffold by in situ Vapor Phase Polymerization, J. Mater. Chem. B. 2018, 6, 4082-4088.
  •  
  • 26. Choi, J. S.; Park, J. S.; Kim, B.; Lee, B.-T.; Yim, J.-H. In Vitro Biocompatibility of Vapour Phase Polymerised Conductive Scaffolds for Cell Lines, Polymer, 2017, 124, 95-100.
  •  
  • 27. Choi, J. S.; Cho, K. Y.; Yim, J.-H. Micro-patterning of Vapor-phase Polymerized Poly(3,4-ethylenedioxythiophene) (PEDOT) Using Ink-jet Printing/soft Lithography, Eur. Polym. J. 2010, 46, 389-396.
  •  
  • 28. Li, Q.; Horn, M.; Wang, Y.; MacLeod, J.; Motta, N.; Liu, J. A Review of Supercapacitors Based on Graphene and Redox-Active Organic Materials. Materials. 2019, 12, 703.
  •  
  • 29. Etacheri, V.; Marom, R.; Elazari, R.; Salitra, G.; Aurbach, D. Challenges in the Development of Advanced Li-ion Batteries: A Review. Energy Environ. Sci. 2011, 4, 3243-3262.
  •  
  • 30. Simon, P.; Gogotsi, Y. Materials for Electrochemical Capacitors. Nat. Mater. 2008, 7, 845-854.
  •  
  • 31. González, A.; Goikolea, E.; Barrena, J. A.; Mysyk, R. Review on Supercapacitors: Technologies and Materials. Renew. Sustain Energy Rev. 2016, 58, 1189-1206.
  •  
  • 32. Lu, X.; Yu, M.; Wang, G.; Tong, Y.; Li, Y. Flexible Solid-state Supercapacitors: Design, Fabrication and Applications. Energy Environ. Sci. 2014, 7, 2160-2181.
  •  
  • 33. Duay, J.; Gillette, E.; Hu, J.; Lee, S. B. Controlled Electrochemical Deposition and Transformation of Hetero-nanoarchitectured Electrodes for Energy Storage, ACS Nano 2013,7, 1200-1214.
  •  
  • 34. Saravanakumar, B.; Purushothaman, K. K.; Muralidharan, G. High Performance Supercapacitor Based on Carbon Coated V2O5 Nanorods, J. Electroanal. Chem. 2015, 758, 111-116.
  •  
  • 35. Zhou, C.; Zhang, Y.; Li, Y.; Liu, J. Construction of High-capacitance 3D CoO@ Polypyrrole Nanowire Array Electrode for Aqueous Asymmetric Supercapacitor, Nano Lett. 2013, 13, 2078-2085
  •  
  • 36. Lu, Q.; Zhou, Y. Synthesis of Mesoporous Polythiophene/MnO2 Nanocomposite and Its Enhanced Pseudocapacitive Properties, J. Power Sources 2011, 196, 4088-4094.
  •  
  • 37. Wu, Q.; Xu, Y.; Yao, Z.; Liu, A.; Shi, G. Supercapacitors Based on Flexible Graphene/polyaniline Nanofiber Composite Films, ACS Nano 2010, 4, 1963-1970.
  •  
  • 38. Kim, Y. J.; Kang, H. J.; Moerk, C. T.; Lee, B.-T.; Choi, J. S.; Yim, J. H. Flexible, Biocompatible, and Electroconductive Polyurethane foam Composites Coated with Graphene Oxide for Ammonia Detection. Sens. Actuators, B. 2021, 344, 130269.
  •  
  • 39. Choi, K. S.; Liu, F.; Choi, J. S.; Seo, T. S. Fabrication of Free-standing Multilayered Graphene and Poly(3,4-ethylenedioxythiophene) Composite Films with Enhanced Conductive and Mechanical Properties, Langmuir. 2010, 26, 12902-12908.
  •  
  • 40. Gray, R. L.; Lee, R. E. Scorch Inhibitors for Flexible Polyurethanes. Plastics Additives 1998, 537-575.
  •  
  • 41. Sudesh; Kumar, N.; Das, S.; Bernhard, C.; Varma, G. D. Effect of Graphene Oxide Doping on Superconducting Properties of Bulk MgB2, Supercond. Sci. Technol. 2013, 26, 095008.
  •  
  • 42. Ahmad, S.; Khan, I.; Husain A.; Khan A.; Asiri, A. M. Electrical Conductivity Based Ammonia Sensing Properties of Polypyrrole/MoS2 Nanocomposite. Polymers. 2020, 12, 3047.
  •  
  • 43. Fernandez, F.D.M.; Khadka, R.; Yim, J.-H. Highly Porous, Soft, and Flexible Vaporphase Polymerized Polypyrrole-styrene-ethylene-butylene-styrene Hybrid Scaffold as Ammonia and Strain Sensor, RSC Adv. 2020, 10, 22533-22541.
  •  
  • 44. Bhat, N. V.; Gadre, A. P.; Bambole, V. A. Structural, Mechanical, and Electrical Properties of Electropolymerized Polypyrrole Composite Films, J. Appl. Polym. Sci. 2001, 80, 2511-2517.
  •  
  • 45. Huang, Y.; Jiao, W.; Chu, Z.; Wang, S.; Chen, L.; Nie, X.; Wang, R.; He, X. High Sensitivity, Humidity-independent, Flexible NO2 and NH3 Gas Sensors Based on SnS2 Hybrid Functional Graphene Ink, ACS Appl. Mater. Interfaces. 2020, 12, 1997-2004.
  •  
  • 46. Kim, Y. J.; Selvam, S.; Yim, J.-H. Preparation of Porous TPU-PPy Flexible Composite Using 3D Printer and Its Application as Electrode Scaffold for Energy Storage Devices. Polym. Korea. 2022, 46, 389-396.
  •  
  • Polymer(Korea) 폴리머
  • Frequency : Bimonthly(odd)
    ISSN 0379-153X(Print)
    ISSN 2234-8077(Online)
    Abbr. Polym. Korea
  • 2022 Impact Factor : 0.4
  • Indexed in SCIE

This Article

  • 2023; 47(4): 453-462

    Published online Jul 25, 2023

  • 10.7317/pk.2023.47.4.453
  • Received on Feb 15, 2023
  • Revised on Apr 19, 2023
  • Accepted on Apr 19, 2023

Correspondence to

  • Jin-Heong Yim

  • Division of Advanced Materials Engineering, Kongju National University, 1223-24 Cheonandaero, Cheonan, Chungnam 31080, Korea

  • E-mail: jhyim@kongju.ac.kr