Article
  • Effects of Maleic Anhydride Content on Thermomechanical and Mechanical Properties of Maleated Natural Rubber

  • Nabil Hayeemasae*, ** , Mohamad Irfan Fathurrohman*** , and Abdulhakim Masa**, ****,†

  • *Department of Rubber Technology and Polymer Science, Faculty of Science and Technology, Prince of Songkla University, Pattani Campus, Pattani, 94000, Thailand
    **Research Unit of Advanced Elastomeric Materials and Innovations for BCG Economy (AEMI), Faculty of Science and Technology, Prince of Songkla University, Pattani Campus, Pattani, 94000, Thailand
    ***Indonesian Rubber Research Institute, Salak Street No. 1 Bogor, 16128, Indonesia
    ****Rubber Engineering & Technology Program, International College, Prince of Songkla University, Hat Yai, Songkhla, 90110, Thailand

  • 무수 말레이산 함량에 따른 말레인산 천연고무의 열적 기계적 물성 연구

  • Reproduction, stored in a retrieval system, or transmitted in any form of any part of this publication is permitted only by written permission from the Polymer Society of Korea.

References
  • 1. Phinyocheep, P. Chemical Modification of Natural Rubber (NR) for Improved Performance. In Chemistry, Manufacture and Applications of Natural Rubber; Kohjiya, S., Ikeda, Y., Eds.; Woodhead Publishing: Cambridge, 2014; pp 68-118.
  •  
  • 2. Wongthong, P.; Nakason, C.; Pan, Q.; Rempel, G. L.; Kiatkamjornwong, S. Modification of Deproteinized Natural Rubber via Grafting Polymerization with Maleic Anhydride. Eur. Polym. J. 2013, 49, 4035-4046.
  •  
  • 3. Nakason, C.; Saiwari, S.; Kaesaman, A. Rheological Properties of Maleated Natural Rubber/Polypropylene Blends with Phenolic Modified Polypropylene and Polypropylene-g-Maleic Anhydride Compatibilizers. Polym. Test. 2006, 25, 413-423.
  •  
  • 4. Nakason, C.; Saiwaree, S.; Tatun, S.; Kaesaman, A. Rheological, Thermal and Morphological Properties of Maleated Natural Rubber and Its Reactive Blending with Poly(methyl methacrylate). Polym. Test. 2006, 25, 656-667.
  •  
  • 5. Nakason, C.; Kaesaman, A.; Samoh, Z.; Homsin, S.; Kiatkamjornwong, S. Rheological Properties of Maleated Natural Rubber and Natural Rubber Blends. Polym. Test. 2002, 21, 449-455.
  •  
  • 6. Ismail, H.; Rusli, A.; Rashid, A. A. Maleated Natural Rubber as a Coupling Agent for Paper Sludge Filled Natural Rubber Composites. Polym. Test. 2005, 24, 856-862.
  •  
  • 7. Brydson, J. A. Rubber Chemistry; Applied Science Publishers: London, 1978.
  •  
  • 8. Nakason, C.; Kaesaman, A.; Samoh, Z.; Homsin, S.; Kiatkamjornwong, S. Rheological and Curing Behavior of Reactive Blending, I. Maleated Natural Rubber-Cassava Starch. J. App. Polym. Sci. 2001, 81, 2803-2813.
  •  
  • 9. Hayeemasae, N.; Sensem, Z.; Sahakaro, K.; Ismail, H. Maleated Natural Rubber/Halloysite Nanotubes Composites. Processes 2020, 8, 286.
  •  
  • 10. Nakason, C.; Kaesaman, A.; Supasanthitikul, P. The Grafting of Maleic Anhydride onto Natural Rubber. Polym. Test. 2004, 23, 35-41.
  •  
  • 11. Vennemann, N.; Bokamp, K.; Broker, D. Crosslink Density of Peroxide Cured TPV. Macromol. Symp. 2006, 245-246, 641-650.
  •  
  • 12. Kangwansupamonkon, W.; Gilbert, R. G.; Kiatkamjornwong, S. Modification of Natural Rubber by Grafting with Hydrophilic Vinyl Monomers. Macromol. Chem. Phys. 2005, 206, 2450-2460.
  •  
  • 13. Sahakaro, K.; Beraheng, S. Reinforcement of Maleated Natural Rubber by Precipitated Silica. J. Appl. Polym. Sci. 2008, 109, 3839-3848.
  •  
  • 14. Ichazo, M. N.; Albano, C.; Hernandez, M.; Gonzalez, J.; Pena, J. Characterization of Natural Rubber/Cassava Starch/Maleated Natural Rubber Formulations. Rev. Latinoam. Metal. Mater. 2011, 31, 71-84.
  •  
  • 15. Masa, A.; Soontaranon, S.; Hayeemasae, N. Influence of Sulfur/Accelerator Ratio on Tensile Properties and Structural Inhomogeneity of Natural Rubber. Polym. Korea 2020, 44, 519-526.
  •  
  • 16. Vennemann, N.; Wu, M. Thermoelastic Properties and Relaxation Behavior of S-SBR/Silica Vulcanizates. Rubber World 2012, 246, 18-23.
  •  
  • 17. Hayeemasae, N.; Soontaranon, S.; Masa, A. Influence of Different Vulcanizing Agents on Structures and Properties of Sepiolite-Filled Natural Rubber Composites. Express Polym. Lett. 2023, 17, 181-195.
  •  
  • 18. Promsung, R.; Nakaramontri, Y.; Uthaipan, N.; Kummerlowe, C.; Johns, J.; Vennemann, N.; Kalkornsurapranee, E. Effects of Protein Contents in Different Natural Rubber Latex Forms on the Properties of Natural Rubber Vulcanized with Glutaraldehyde. Express Polym. Lett. 2021, 15, 308-318.
  •  
  • 19. Srinivasan, N.; Bokamp, K.; Vennemann, N. New test method for the characterisation of filled elastomers. Kautsch. Gummi Kunstst. 2005, 58, 650-655.
  •  
  • 20. Rodgers, B. Rubber Compounding: Chemistry and Applications; CRC Press: New York, 2015.
  •  
  • 21. Pongdong, W.; Kummerlowe, C.; Vennemann, N.; Thitithammawong, A.; Nakason, C. A Comparative Investigation of Rice Husk Ash and Siliceous Earth as Reinforcing Fillers in Dynamically Cured Blends of Epoxidized Natural Rubber (ENR) and Thermoplastic Polyurethane (TPU). J. Polym. Environ. 2018, 26, 1145-1159.
  •  
  • 22. Chatterjee, T.; Vennemann, N.; Naskar, K. Temperature Scanning Stress Relaxation Measurements: A Unique Perspective for Evaluation of the Thermomechanical Behavior of Shape Memory Polymer Blends. J. Appl. Polym. Sci. 2018, 135, 45680.
  •  
  • 23. Matchawet, S.; Kaesaman, A.; Vennemann, N.; Kumerlowe, C.; Nakason, C. Effects of Imidazolium Ionic Liquid on Cure Characteristics, Electrical Conductivity and Other Related Properties of Epoxidized Natural Rubber Vulcanizates. Eur. Polym. J. 2017, 87, 344-359.
  •  
  • Polymer(Korea) 폴리머
  • Frequency : Bimonthly(odd)
    ISSN 0379-153X(Print)
    ISSN 2234-8077(Online)
    Abbr. Polym. Korea
  • 2022 Impact Factor : 0.4
  • Indexed in SCIE

This Article

  • 2023; 47(5): 565-573

    Published online Sep 25, 2023

  • 10.7317/pk.2023.47.5.565
  • Received on Jan 25, 2023
  • Revised on Jul 6, 2023
  • Accepted on Jul 12, 2023

Correspondence to

  • Abdulhakim Masa

  • **Research Unit of Advanced Elastomeric Materials and Innovations for BCG Economy (AEMI), Faculty of Science and Technology, Prince of Songkla University, Pattani Campus, Pattani, 94000, Thailand
    ****Rubber Engineering & Technology Program, International College, Prince of Songkla University, Hat Yai, Songkhla, 90110, Thailand

  • E-mail: abdulhakim.m@psu.ac.th