Article
  • Effects of Nanosilica on the Mechanical Properties and Swelling Resistance of EPDM/NBR Nanocomposites
  • S. Dhanasekar , M. S. Ravi Theja*, S. Baskar**, and S. Vishvanathperumal

  • Department of Mechanical Engineering, S.A. Engineering College, Chennai - 600077, Tamilnadu, India
    *Department of Mechanical Engineering, Sri Eshwar College of Engineering, Coimbatore, Tamilnadu - 641202, Tamilnadu, India
    **Centre for Nonlinear Systems, Chennai Institute of Technology, Kundrathur, Chennai - 600069, Tamilnadu, India

  • EPDM/NBR 나노복합체의 기계적 물성과 팽윤 저항에 대한 Nanosilica 영향 연구
  • Reproduction, stored in a retrieval system, or transmitted in any form of any part of this publication is permitted only by written permission from the Polymer Society of Korea.

References
  • 1. Vishvanathperumal, S.; Navaneethakrishnan, V.; Anand, G.; Gopalakannan, S. Evaluation of Crosslink Density Using Material Constants of Ethylene-propylene-diene Monomer/styrene-butadiene Rubber with Different Nanoclay Loading: Finite Element Analysis-simulation and Experimental. Adv. Sci., Eng. Med. 2020, 12, 632-642.
  •  
  • 2. Anand, G.; Vishvanathperumal, S. Properties of SBR/NR Blend: The Effects of Carbon Black/Silica (CB/SiO2) Hybrid Filler and Silane Coupling Agent. Silicon 2022, 14, 9051-9060.
  •  
  • 3. Dhanasekar, S.; Baskar, S.; Vishvanathperumal, S. Halloysite Nanotubes Effect on Cure and Mechanical Properties of EPDM/NBR Nanocomposites. J. Inorg. Org. Polym. Mater. 2023, 1-13.
  •  
  • 4. Ragupathy, K.; Prabaharan, G.; Pragadish, N.; Vishvanathperumal, S. Effect of Silica Nanoparticles and Modified Silica Nanoparticles on the Mechanical and Swelling Properties of EPDM/SBR Blend Nanocomposites. Silicon 2023, 1-14.
  •  
  • 5. Das, R. K.; Ragupathy, K.; Kumar, T. S.; Vishvanathperumal, S. Effect of Halloysite Nanotubes (HNTs) on Mechanical Properties of EPDM/NBR Blend-Nanocomposites. Polym. Korea 2023, 47, 221-232.
  •  
  • 6. Ai, C.; Gong, G.; Zhao, X.; Liu, P. Determination of Carboxyl Content in Carboxylated Nitrile Butadiene Rubber (XNBR) After Degradation via Olefin Cross Metathesis. Polym. Test. 2017, 60, 250-252.
  •  
  • 7. Sundar, R.; Mohan, S. K.; Vishvanathperumal, S. Effect of Surface Modified Halloysite Nanotubes (mHNTs) on the Mechanical Properties and Swelling Resistance of EPDM/NBR Nanocomposites. Polym. Korea 2022, 46, 728-743.
  •  
  • 8. Doufnoune, R.; Haddaoui, N. Effects of Surface Functionalized Partially Reduced Graphene Oxide and Different Compatibilizers on the Properties and Structure of PP/EPR Nanocomposites. J. Polym. Res. 2017, 24, 138-147.
  •  
  • 9. Vishvanathperumal, S.; Anand, G. Effect of Nanoclay/nanosilica on the Mechanical Properties, Abrasion and Swelling Resistance of EPDM/SBR Composites. Silicon 2020, 12, 1925-1941.
  •  
  • 10. Vishvanathperumal, S.; Anand, G. Effect of Nanosilica and Crosslinking System on the Mechanical Properties and Swelling Resistance of EPDM/SBR Nanocomposites with and Without TESPT. Silicon 2021, 13, 3473-3497.
  •  
  • 11. Kueseng, P.; Sae-oui, P.; Rattanasom, N. Mechanical and Electrical Properties of Natural Rubber and Nitrile Rubber Blends Filled with Multi-wall Carbon Nanotube: Effect of Preparation Methods, Polym. Test. 2013, 32, 731-738.
  •  
  • 12. Chow, W. S.; Bakar, A. A.; Ishak, Z. M.; Karger-Kocsis, J.; Ishiaku, U. S. Effect of Maleic Anhydride-grafted Ethylene–propylene Rubber on the Mechanical, Rheological and Morphological Properties of Organoclay Reinforced Polyamide 6/polypropylene Nanocomposites. Eur. Polym. J. 2005, 41, 687-696.
  •  
  • 13. Bonilla-Cruz, J.; Hernández-Mireles, B.; Mendoza-Carrizales, R.; Ramírez-Leal, L. A.; Torres-Lubián, R.; RamosdeValle, L. F.; Paul, D. R.; Saldívar-Guerra, E. Chemical Modification of Butyl Rubber with Maleic Anhydride via Nitroxide Chemistry and Its Application in Polymer Blends. Polymers 2017, 9, 63.
  •  
  • 14. Azizli, M. J.; Mokhtary, M.; Khonakdar, H. A.; Goodarzi, V.; Hybrid Rubber Nanocomposites Based on XNBR/EPDM: Select the Best Dispersion Type from Different Nanofillers in the Presence of a Compatibilizer. J. Inorg. Org. Polym. Mater. 2020, 30, 2533-2550.
  •  
  • 15. Rafiee, E.; Shahebrahimi, S.; Feyzi, M.; Shaterzadeh, M. Optimization of Synthesis and Characterization of Nanosilica Produced from Rice Husk (a common waste material). Int. Nano Lett. 2012, 2, 29.
  •  
  • 16. Vishvanathperumal, S.; Navaneethakrishnan, V.; Gopalakannan, S. The Effect of Nanoclay and Hybrid Filler on Curing Characteristics, Mechanical Properties and Swelling Resistance of Ethylene-vinyl Acetate/styrene Butadiene Rubber Blend Composite. J. Adv. Micros. Res. 2018, 13, 469-476.
  •  
  • 17. Liu, Y.; Cao, L.; Yuan, D.; Chen, Y. Design of Super-tough Co-continuous PLA/NR/SiO2 TPVs with Balanced Stiffness-toughness Based on Reinforced Rubber and Interfacial Compatibilization. Compos. Sci. Technol. 2018, 165, 231-239.
  •  
  • 18. Changwoon, N.; Mong-Young, H.; Rhee, J. M.; Tae-Ho, Y. Plasma Surface Modification of Silica and Its Effect on Properties of Styrene–butadiene Rubber Compound, Polym. Int. 2002, 51, 510-518.
  •  
  • 19. Shanmugharaj, A. M.; Bhowmick, A. K. Dynamic Mechanical Properties of Styrene-butadiene Rubber Vulcanizate Filled with Electron Beam Modified Surface-treated Dual-phase Filler, J. Appl. Polym. Sci. 2010, 88, 2992-3004.
  •  
  • 20. Lee, J. Y.; Lee, T.; Kim, K.; Kim, B.; Kwag, G.; Kim, J. Y.; Ji, S.; Kim, W.; Paik, H. J. Poly(styrene-r-butadiene)-b-poly(poly(ethylene glycol) methyl ether methacrylate) as a Silica Dispersant in Rubber Compounds, Polym. Int. 2014, 63, 908-914.
  •  
  • 21. Xu, T.; Jia, Z.; Luo, Y.; Jia, D.; Zheng, P. Interfacial Interaction Between the Epoxidized Natural Rubber and Silica in Natural Rubber/silica Composites, Appl. Surface Sci. 2015, 328, 306-313.
  •  
  • 22. Liu, Y.; Cao, L.; Yuan, D.; Chen, Y. Design of Super-tough Co-continuous PLA/NR/SiO2 TPVs with Balanced Stiffness-toughness Based on Reinforced Rubber and Interfacial Compatibilization, Compos. Sci. Technol. 2018, 165, 231-239.
  •  
  • 23. Chen, L.; Jia, Z.; Tang, Y.; Wu, L.; Luo, Y.; Jia, D. Novel Functional Silica Nanoparticles for Rubber Vulcanization and Reinforcement, Compos. Sci. Technol. 2017, 144, 11-17.
  •  
  • 24. Castellano, M.; Conzatti, L.; Turturro, A.; Costa, G.; Busca, G. Influence of the Silane Modifiers on the Surface Thermodynamic Characteristics and Dispersion of the Silica Into Elastomer Compounds, J. Phys. Chem. B 2007, 111, 4495-4502.
  •  
  • 25. Kaewsakul, W.; Sahakaro, K.; Dierkes, W. K.; Noordermeer, J. W. Mechanistic Aspects of Silane Coupling Agents with Different Functionalities on Reinforcement of Silicafilled Natural Rubber Compounds, Polym. Eng. Sci. 2015, 55, 836-842.
  •  
  • 26. Zheng, J.; Han, D.; Zhao, S.; Ye, X.; Wang, Y.; Wu, Y.; Dong, D. Liu, J.; Wu, X.; Zhang, L. Constructing a Multiple Covalent Interface and Isolating Disperion Structure in Silica/rubber Nanocomposites with Excellent Dynamic Performance, ACS Appl. Mater. Interfaces 2018, 10, 19922-19931.
  •  
  • 27. Zhang, C.; Tang, Z.; Guo, B.; Zhang, L. Significantly Improved Rubber-silica Interface via Subtly Controlling Surface Chemistry of Silica, Compos. Sci. Technol. 2018, 156, 70-77.
  •  
  • 28. Li, Y.; Han, B.; Wen, S.; Lu, Y.; Yang, H.; Zhang, L.; Liu, L. Effect of the Temperature on Surface Modification of Silica and Properties of Modified Silica Filled Rubber Composites, Compos. Part A 2014, 62, 52-59.
  •  
  • 29. Vansant, E. F.; Van Der Voort, P.; Vrancken, K. C. Characterization and Chemical Modification of the Silica Surface. Elsevier 1995.
  •  
  • 30. Lin, J.; Chen, H.; Yuan, Y.; Ji, Y. Mechanochemically Conjugated PMHS/nano-SiO2 Hybrid and Subsequent Optimum Grafting Density Study, Appl. Surface Sci. 2011, 257, 9024-9032.
  •  
  • 31. Moitra, N.; Ichii, S.; Kamei, T.; Kanamori, K.; Zhu, Y.; Takeda, K.; Nakanishi, K.; Shimada, T. Surface Functionalization of Silica by Si-H Activation of Hydrosilanes, J. Am. Chem. Soc. 2014, 136, 11570-11573.
  •  
  • 32. Vishvanathperumal, S.; Anand, G. Effect of Nanosilica on the Mechanical Properties, Compression Set, Morphology, Abrasion and Swelling Resistance of Sulphur Cured EPDM/SBR Composites. Silicon 2022, 14, 3523-3534.
  •  
  • 33. Ganeche, P. S.; Balasubramanian, P.; Vishvanathperumal, S. Halloysite Nanotubes (HNTs)-Filled Ethylene-Propylene-Diene Monomer/Styrene-Butadiene Rubber (EPDM/SBR) Composites: Mechanical, Swelling, and Morphological Properties. Silicon 2022, 14, 6611-6620.
  •  
  • 34. Vishvanathperumal, S.; Gopalakannan, S. Reinforcement of Ethylene Vinyl Acetate with Carbon Black/silica Hybrid Filler Composites. Appl. Mech. Mater. 2016, 852, 16-22.
  •  
  • 35. Senthilvel, K.; Vishvanathperumal, S.; Prabu, B.; John Baruch, L. Studies on the Morphology, Cure Characteristics and Mechanical Properties of Acrylonitrile Butadiene Rubber with Hybrid Filler (carbon black/silica) Composite. Polym. Polym. Compos. 2016, 24, 473-480.
  •  
  • 36. Vishvanathperumal, S.; Gopalakannan, S. Swelling Properties, Compression Set Behavior and Abrasion Resistance of Ethylene-propylene-diene Rubber/styrene Butadiene Rubber Blend Nanocomposites. Polym. Korea 2017, 41, 433-442.
  •  
  • 37. Zhang, C.; Tang, Z.; Guo, B.; Zhang, L. Significantly Improved Rubber-silica Interface via Subtly Controlling Surface Chemistry of Silica. Compos. Sci. Technol. 2018, 156, 70-77.
  •  
  • 38. Ryu, C.; Kim, S. J.; Kim, D.; Kaang, S.; Seo, G. The Effect of Surface Area of Silicas on Their Reinforcing Performance to Styrene-butadiene Rubber Compounds. Elastomers Compos. 2016, 51, 128-137.
  •  
  • 39. Surya, I.; Ismail, H.; Azura, A. R. The Comparison of Alkanol Amide and Silane Coupling Agent on the Properties of Silica- Filled Natural Rubber (SMR-L) Compounds. Polym. Test. 2014, 40, 24-32.
  •  
  • 40. Ravi Theja, M. S.; Kilari, N.; Vishvanathperumal, S.; Navaneethakrishnan, V. Modeling Tensile Modulus of Nanoclay-filled Ethylene–propylene–diene Monomer/styrene–butadiene Rubber Using Composite Theories. J. Rubber Res. 2021, 24, 847-856.
  •  
  • 41. Peng, H.; Liu, L.; Luo, Y.; Wang, X.; Jia, D. Effect of 3-Propionylthio-1-propyltrimethoxylsilane on Structure, Mechanical, and Dynamic Mechanical Properties of NR/Silica Composites. Polym. Compos. 2009, 30, 955-961.
  •  
  • 42. Vishvanathperumal, S.; Gopalakannan, S. Effects of the Nanoclay and Crosslinking Systems on the Mechanical Properties of Ethylene-propylene-diene Monomer/styrene Butadiene Rubber Blends Nanocomposite. Silicon 2019, 11, 117-135.
  •  
  • 43. Dileep, P.; Narayanankutty, S. K. Styrenated Phenol Modified Nanosilica for Improved Thermo-oxidative and Mechanical Properties of Natural Rubber. Polym. Test. 2020, 82, 106302.
  •  
  • 44. Zhang, X.; Cui, H.; Song, L.; Ren, H.; Wang, R.; He, A. Elastomer Nanocomposites with Superior Dynamic Mechanical Properties via Trans-1, 4-poly(butadiene-co-isoprene) Incorporation. Compos. Sci. Technol. 2018, 158, 156-163.
  •  
  • 45. Mostafa, A.; Kasem, A. A.; Bayoumi, M. R.; El-Sebaie, M. G. Effect of Carbon Black Loading on the Swelling and Compression Set Behavior of SBR and NBR Rubber Compounds. Mater. Design 2009, 30, 1561-1568.
  •  
  • 46. Aravinth, V.; Gurumoorthi, G.; Vishvanathperumal, S.; Navaneethakrishnan, V. Effect of Modified Nanographene Oxide on the Mechanical and Swelling Properties of Silicone Rubber Nanocomposites. Polym. Korea 2023, 47, 288-302.
  •  
  • 47. Govindan, K.; Ramabalan, S.; Vishvanathperumal, S.; Chockalingam, S., Influence of Halloysite Nanotubes on Mechanical and Swelling Properties of Silicone Rubber Compound. J. Polym. Res. 2023, 30, 1-17.
  •  
  • 48. Zhang, H.; Gao, Y.; Li, F.; Zhang, Z.; Liu, Y.; Zhao, G. Influence of Silane Coupling Agents on Vulcanised Natural Rubber: Dynamic Properties and Heat Buildup. Plastics, Rubber and Compos 2016, 45, 9-15.
  •  
  • Polymer(Korea) 폴리머
  • Frequency : Bimonthly(odd)
    ISSN 0379-153X(Print)
    ISSN 2234-8077(Online)
    Abbr. Polym. Korea
  • 2022 Impact Factor : 0.4
  • Indexed in SCIE

This Article

  • 2023; 47(5): 613-627

    Published online Sep 25, 2023

  • 10.7317/pk.2023.47.5.613
  • Received on May 5, 2023
  • Revised on Jun 26, 2023
  • Accepted on Aug 8, 2023

Correspondence to

  • S. Dhanaseka
  • Department of Mechanical Engineering, S.A. Engineering College, Chennai - 600077, Tamilnadu, India

  • E-mail: gurusekar1989@gmail.com