Article
  • Study on the Crosslinking System for Molded-In Foaming (MIF) Process

  • Hyo-Jun Kim , Geon-Uk Park*, Jae-Keun Yu*, Sung-hyun Choi*, Min-Young Shon† , and Myung-Jun Moon†

  • Department of Industrial Chemistry, Pukyong National University, Busan 48512, Korea
    *Korea Institute of Footwear & Leather Technology, Busan 47154, Korea

  • Molded-In Foaming(MIF) 공정에 적합한 가교 시스템에 관한 연구

  • 김효준 · 박건욱* · 유재근* · 최성현* · 손민영† · 문명준†

  • 부경대학교 공업화학과, *한국신발피혁연구원

  • Reproduction, stored in a retrieval system, or transmitted in any form of any part of this publication is permitted only by written permission from the Polymer Society of Korea.

References
  • 1. Harvey, A. J. Footwear Materials and Process Technology; LASRA Publication: Palmerston North, 1992.
  •  
  • 2. Ames, K. A. Elastomers for Shoe Applications. Rubber Chem. Technol. 2004, 77, 413-475.
  •  
  • 3. Bae, J. W. Rubber Technology Trends for Footwear. Rubber Technology 2014, 15, 1-9.
  •  
  • 4. Lee, J. Y.; Park, C. H.; Kim, D. S. Development Trend of Polymer Modification for Shoe. Polym. Sci. Technol. 2002, 13, 447-452.
  •  
  • 5. Kim, M. G.; Song, H. Y.; Kim, D. G.; Kim, H. J.; Park, G. U.; Yu, J. K.; Hyun, K. The Study on the Rheological Properties of Polymer Matrix for MIF(Molded-In Foaming) Process; Elastom. Compos. 2014, 4, 323-329.
  •  
  • 6. Lee, S. H.; Kim, D. K.; Lim, S. W.; Park, E. Y.; Park, T. S.; Hyun, K. The Investigation of Rheological Properties Development for Polymer Matrix Including Foaming Agent. Elastom. Compos. 2016, 51, 24-30.
  •  
  • 7. Lee, S. H.; Song, H. Y.; Kim, D. K.; Lim, S. W.; Park, E. Y.; Hyun, K. Investigation of Foaming Cell Development for Epoxy Resin with Blowing and Curing Agent by Rheological Properties. Macromol. Res. 2017, 25, 325-334.
  •  
  • 8. Kong, H. J.; Lee, S. H.; Kim, D. K.; Kim, H. J.; Park, G. W.; Hyun, K. Investigation of Thermoplastic Elastomer (TPE) Foaming Process Using Blowing Agent by Rheological and Morphological Methods. J. Appl. Polym. Sci. 2018, 136, 47358.
  •  
  • 9. Eisenberg, A.; Kim, J. S. Introduction to Ionomers; John Wiley & Sons: New York, 1998.
  •  
  • 10. Eisenberg, A.; King, M. Ion Containing Polymers,Academic Press, New York, 1977.
  •  
  • 11. Eisenberg, A,; Smith, P.; Zhou, Z. L. Compatibilization of the Polystyrene/Poly(Ethyl Acrylate) and Polystyrene/Polyisoprene Systems Through Ionic Interactions. Polym. Eng. Sci. 1982, 17, 1117-1122.
  •  
  • 12. Smith, P.; Eisenberg, A. Ionomeric blends. I. Compatibilization of the Polystyrene–poly(ethyl acrylate) System via Ionic Interactions. J. Polym. Lett. Ed. 1983, 21, 223-230.
  •  
  • 13. Zhou, Z. L.; Eisenberg, A. Ionomeric Blends. II. Compatibility and Dynamic Mechanical Properties of Sulfonated Cis-1,4-Polyisoprenes and Styrene/4-vinylpyridine Copolymer Blends. J. Polym. Sci., Polym. Phys. Ed. 1983, 21, 595-630.
  •  
  • 14. Rutkowska, M.; Eisenberg, A. Ionomeric Blends. IV. Miscibility of Urethane Elastomers with Styrene-styrene Sulfonic Acid Copolymer. J. Appl. Polym. Sci. 1984, 29, 755-762.
  •  
  • 15. Wakabayashi, K.; Register, R. A. Morphological Origin of the Multistep Relaxation Behavior in Semicrystalline Ethylene/methacrylic Acid Ionomers. Macromolecules 2006, 39, 1079-1086.
  •  
  • 16. Gomez, G. H.; Gasparini, T. M.; Canevarolo, S. V. Solid-State Morphology Evolution of Sodium Neutralized Poly(ethylene-Ran-Methacrylic Acid) Ionomer under Dry and Wet Thermal Annealing. Mater. Res. 2019, 22, e20180592.
  •  
  • 17. Eisenberg, A. Ions in Polymers; American Chemical Society: Washington, D.C., 1980.
  •  
  • 18. Hollida, L. Ionic polymers; Wiley: New York, 1975.
  •  
  • 19. Pal, S.; Naskar, K. Influence of Stearic Acid in Zinc Based Maleated-EPM ionomer: A Novel Approach Towards Recyclability. Composites Part B, 2019, 176, 107296.
  •  
  • 20. Thaworn, K.; Buahom, P.; Areerat, S. Effects of Organic Peroxides on the Curing Behavior of EVA Encapsulant Resin. J. Polymer Chemistry, 2012, 2, 77-85.
  •  
  • 21. Coleman, M. M.; Lee, J. Y.; Painter, P. C. Acid Salts and the Structure of Ionomers. Macromolecules, 1990, 23, 2339-2345.
  •  
  • 22. Brozoski, B. A.; Coleman, M. M.; Painter, P. C. Local Structures in Ionomer Multiplets. A Vibrational Spectroscopic Analysis. Macromolecules, 1984,17, 230-234.
  •  
  • 23. MacKnight, W. J.; McKenna, L. W.; Read, B. E.; Stein, R. S. Properties of Ethylene-methacrylic Acid Copolymers and Their Sodium Salts. Infrared Studies. J. Phys. Chem. 1968, 72, 1122-1126.
  •  
  • 24. Zeng, X.; Yamane, H.; Takahashi, M.; Masuda, T. Structure and Properties of Ionomers Based on Ethylene-co-Methacrylic Acid Copolymer (EMAA): Effects of Ion Aggregates. Mater. Sci. Res. Int. 1999,5, 28-32.
  •  
  • 25. Dick, J. S.; Annicelli, R. A.; Baddorf, C.; Baranwal, K.; Cable, C. J. Rubber Technology: Compounding and Testing for Performance;Hanser Gardner Publications: Ohio, 2009.
  •  
  • 26. Bianchi, O.; Martins, J. De N.; Fiorio, R.; Oliveira, R. V. B.; Canto, L. B. Changes in Activation Energy and Kinetic Mechanism during EVA Crosslinking, Polym. Testing, 2011, 6, 616-624.
  •  
  • 27. Callais, P. A. Organic Peroxides. In Coating Technology Handbook; Tracton, A., Ed.; CRC Press: Boca Raton, 2006.
  •  
  • 28. Bhagabati, P.; Murugesan, S. Insights into Mechanical, Thermal, and Electrical Properties of Peroxide-Cured Chlorinated Polyethylene/Ethylene Methacrylate Copolymer Blend Vulcanizates. ACS Omega, 2021, 6, 20181-20191.
  •  
  • 29. Akiba, M. A.; Hashim, A. Vulcanization and Crosslinking in Elastomers. Prog. Polym. Sci. 1997, 22, 475-521.
  •  
  • 30. Robinson, A.; Marra, J.; Amberg, L. Ethylene-propylene Rubber Vulcanization with Aralkyl Peroxide and Coagents. Ind. Eng. Chem. Prod. Res. 1962, 1, 78-82.
  •  
  • 31. Gent, A. N. Engineering with Rubber: How to Design Rubber Components, 2nd ed.; Hanser: Munich, 2001.
  •  
  • 32. Product Bulletin, Organic Peroxides: General Catalog: Colombes; Arkema Inc., 2006.
  •  
  • 33. Coran A. Y. Vulcanization. Part V. The formation of crosslinks in the system: natural rubber-sulfur-MBT-zinc ion. Rubber Chem. Technol. 1964, 3, 679-688.
  •  
  • 34. Heideman, G.; Noordermeer, J. W. M.; Datta R. N.; Baarle B. V. Effect of Zinc Complexes as Activator for Sulfur Vulcanization in Various Rubbers, Rubber Chem. Technol. 2005, 2, 245-257.
  •  
  • 35. Kim, Y.; Choi, S. S.; Bae, J. W.; Kim, J. S. Effects of ZnO content on Microstructure and Properties of Maleated EPDM/zinc Oxide Composites. Polym. Bull. 2015, 72, 1163-1175.
  •  
  • Polymer(Korea) 폴리머
  • Frequency : Bimonthly(odd)
    ISSN 0379-153X(Print)
    ISSN 2234-8077(Online)
    Abbr. Polym. Korea
  • 2022 Impact Factor : 0.4
  • Indexed in SCIE

This Article

  • 2023; 47(5): 669-677

    Published online Sep 25, 2023

  • 10.7317/pk.2023.47.5.669
  • Received on Jun 20, 2023
  • Revised on Jul 11, 2023
  • Accepted on Jul 12, 2023

Correspondence to

  • Min-Young Shon, Myung-Jun Moon

  • Department of Industrial Chemistry, Pukyong National University, Busan 48512, Korea

  • E-mail: myshon@pknu.ac.kr, mjmoon@pknu.ac.kr